Oxidative addition of NH3 to a transition-metal complex:: A key step for the metal-mediated derivatization of ammonia?

被引：61
作者：
Braun, T [1 ]
机构：
[1] Univ Bielefeld, Fak Chem, D-33501 Bielefeld, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 32期
关键词：
N-H activation; amido complexes; hydroamination; iridium; oxidative addition;
D O I：
10.1002/anie.200501505
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Bond cleavage with model character? The oxidative addition of ammonia to a transition-metal complex to yield a terminal amido complex was achieved for the first time recently (see scheme). This model reaction might provide new pathways to use ammonia as a feedstock in catalytic reactions. (Chemical Equation Presented) © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：5012 / 5014
页数：3
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