Synthesis, structural characterization of new macrocyclic Schiff base derived from 1,6-bis(2-formylphenyl)hexane and 2,6-diaminopyridine and its metal complexes

被引：0

作者：

Ilhan, Salih ^{[1
]}

Ternel, Hamdi ^{[2
]}

Sunkur, Murat ^{[3
]}

Tegin, Ibrahim ^{[1
]}

机构：

[1] Siirt Univ, Fac Art & Sci, Dept Chem, Siirt, Turkey

[2] Dicle Univ, Fac Educ, Dept Chem, TR-21280 Diyarbakir, Turkey

[3] Batman Univ, Fac Tech Educ, Batman, Turkey

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2008年 / 47卷 / 04期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A macrocyclic ligand has been synthesized by reaction of 2,6-diaminopyridine and 1,6-bis(2-formylphenyl).hexane. Its complexes with Cu(II), Ni(II), Pb(II), Zn(II), Cd(II) and La(III) have been synthesized by the reaction of ligand and Cu(ClO4)(2)center dot 6H(2)O, Ni(ClO4)(2)center dot 6H(2)O, Pb(ClO4)(2)center dot 6H(2)O, Zn(ClO4)(2)center dot 6H(2)O, Cd(ClO4)(2)center dot 6H(2)O and La(ClO4)(3)center dot 6H(2)O, respectively. The ligand and its metal complexes have been characterized. All complexes are diamagnetic while the Cu(II) complex is binuclear.

引用

页码：560 / 564

页数：5

共 23 条

[1] Modern spectroscopic techniques in the characterization of Schiff base macrocyclic ligand and its complexes with transition metals
Chandra, S
Gupta, LK
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2005, 62 (1-3) : 307 - 312
[2] Synthesis, crystal structures and toxicity of bicadmium(II) complexes with macrocyclic, hexaaza-bearing, hydroxyethyl pendants
Gao, J
Xu, XY
Ma, WX
Wang, MY
Song, HB
Yang, XJ
Lu, LD
Wang, X
[J]. JOURNAL OF COORDINATION CHEMISTRY, 2004, 57 (17-18) : 1553 - 1561
[3] ILHAN S, 2008, J COORD CHEM, V25, P1547
[4] ILHAN S, 2008, IN PRESS J MOL STRUC
[5] ILHAN S, 2008, CHINESE J CHEM, V61, P277
[6] ILHAN S, UNPUB INDIAN J CHEM
[7] ILHAN S, 2008, IN PRESS INDIAN J CH, V47
[8] Synthesis and characterization of new macrocyclic Schiff base derived from 2,6-diaminopyridine and 1,7-bis(2-formylphenyl)-1,4,7-trioxaheptane and its Cu(II), Ni(II), Pb(II), Co(III) and La(III) complexes
Ilhan, Salih
Temel, Hamdi
Yilmaz, Ismail
Sekerci, Memet
[J]. POLYHEDRON, 2007, 26 (12) : 2795 - 2802
[9] Synthesis and spectral characterization of macrocyclic NiII complexes derived from various diamines, NiII perchlorate and 1,4-bis(2-carboxyaldehydephenoxy)butane
Ilhan, Salih
Temel, Hamdi
Kilic, Ahmet
Tas, Esref
[J]. TRANSITION METAL CHEMISTRY, 2007, 32 (08) : 1012 - 1017
[10] Synthesis and characterization of a new macrocyclic Schiff base derived from 2,6-diaminopyridine and 1,10-bis(2-formylphenyl)-1,4,7,10-tetraoxadecane and its Cu(II), Ni(II), Pb(II), Co(III) and La(III) complexes
Ilhan, Salih
Temel, Hamdi
[J]. TRANSITION METAL CHEMISTRY, 2007, 32 (08) : 1039 - 1046

← 1 2 3 →