Atom transfer radical polymerization (ATRP) of methyl methacrylate mediated by iron(II) chloride in the presence of polyethers as both solvents and ligands

被引：8
作者：
Ng, Yeap-Hung [1 ]
di Lena, Fabio [1 ]
Chai, Christina L. L. [2 ,3 ]
机构：
[1] Agcy Sci Technol & Res, Inst Chem & Engn Sci, Jurong Isl 627833, Singapore
[2] Agcy Sci Technol & Res, Inst Chem & Engn Sci, Chem Neuros, Singapore 138665, Singapore
[3] Natl Univ Singapore, Dept Pharm, Singapore 117543, Singapore
来源：
MACROMOLECULAR RESEARCH | 2012年 / 20卷 / 06期
关键词：
atom transfer radical polymerization; iron; ligand-free catalysis; poly(ethylene glycol); PHASE-TRANSFER CATALYSTS; POLYETHYLENE-GLYCOL DERIVATIVES; COMPLEXING AGENTS; N; N-DIMETHYLTHIOFORMAMIDE; N-DIMETHYLFORMAMIDE; REACTIVITY; BEHAVIOR; STYRENE; DESIGN;
D O I：
10.1007/s13233-012-0077-3
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Iron(II) chloride in combination with various polyethers form the homogeneous, "green" catalytic mixtures that are capable of promoting the well-controlled atom transfer radical polymerization of methyl methacrylate in the absence of any additional ligands or solvents. With poly(ethylene glycol)s, linear semilogarithmic plots of conversion vs. time and of molecular weight vs. monomer conversion were obtained with polydispersities as low as 1.32. The effects of the polyether structure, molecular weight, and chain-end functionality on the polymerization kinetics were also investigated.
引用
收藏
页码：552 / 558
页数：7
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