Influence of additive on diamond films synthesized using liquid phase electrochemical method

被引:5
作者
Zhang, G. F. [1 ]
He, Y. Y. [1 ]
Hou, X. D. [1 ]
机构
[1] Dalian Univ Technol, State Lab Mat Modificat Laser Ion & Electron Beam, Sch Mat Sci & Engn, Dalian 116024, Peoples R China
来源
FUNCTIONAL AND ELECTRONIC MATERIALS | 2011年 / 687卷
关键词
nano-and micro-crystalline diamond films; electrochemical deposition; growth rate; additive; CARBON-FILMS; ELECTROLYSIS; DEPOSITION;
D O I
10.4028/www.scientific.net/MSF.687.662
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
An attempt was made to deposit nano-crystalline (or amorphous) diamond films on silicon and 316L stainless steel substrates by electrochemical deposition using a high-voltage pulsed generator. Alcoholic organic compounds with various concentrations of deionized water were used as electrolysis solutions. The surface morphology and crystal structure of the films were examined by scanning electron microscopy and Raman spectroscopy. Adding de-ionized water into the reaction solution can enhance the deposition rate of amorphous diamond films. The crystalline structure analysis has confirmed unambiguously the formation of diamond nano- or submicron-crystals in the deposits. It is believed that the ion H of electrochemical production plays quite similar roles to those that take place in chemical vapor deposition methods of diamond growth.
引用
收藏
页码:662 / 666
页数:5
相关论文
共 11 条
  • [1] Structural and chemical characterisation of soot particles formed in Ar/H2/CH4 microwave discharges during nanocrystalline diamond film synthesis
    Aggadi, N.
    Arnas, C.
    Benedic, F.
    Dominique, C.
    Duten, X.
    Silva, F.
    Hassouni, K.
    Gruen, D. M.
    [J]. DIAMOND AND RELATED MATERIALS, 2006, 15 (4-8) : 908 - 912
  • [2] CLEM PG, 2001, Patent No. 6231666
  • [3] [杜景永 DU Jingyong], 2007, [电子显微学报, Journal of Chinese Electronic Microscopy Society], V26, P19
  • [4] [杜景永 DU Jingyong], 2007, [电化学, Electrochemistry], V13, P58
  • [5] Deposition of amorphous diamond films on different substrates by electrolysis of methanol solution
    He, Y. Y.
    Zhang, G. F.
    Li, G. Q.
    Hou, X. D.
    [J]. SURFACE ENGINEERING (ICSE 2007), 2008, 373-374 : 264 - 267
  • [6] Diamond-like carbon layers grown by electrochemical method-structural study
    Kulesza, S.
    Szatkowski, J.
    Lulinska, E.
    Kozanecki, M.
    [J]. ENERGY CONVERSION AND MANAGEMENT, 2008, 49 (09) : 2487 - 2489
  • [7] Hydrogen in nano-diamond films
    Michaelson, S
    Hoffman, A
    [J]. DIAMOND AND RELATED MATERIALS, 2005, 14 (3-7) : 470 - 475
  • [8] ATTEMPT TO GROW DIAMOND PHASE CARBON-FILMS FROM AN ORGANIC SOLUTION
    NAMBA, Y
    [J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1992, 10 (05): : 3368 - 3370
  • [9] Synthesis of diamondlike films by an electrochemical method at atmospheric pressure and low temperature
    Novikov, VP
    Dymont, VP
    [J]. APPLIED PHYSICS LETTERS, 1997, 70 (02) : 200 - 202
  • [10] Investigation of phases in the carbon films deposited by electrolysis of ethanol liquid phase using Raman scattering
    Sun, Z
    Sun, Y
    Wang, X
    [J]. CHEMICAL PHYSICS LETTERS, 2000, 318 (4-5) : 471 - 475