Metal-free imination of sulfoxides and sulfides

被引:42
作者
Cho, GY [1 ]
Bolm, C [1 ]
机构
[1] Univ Aachen, Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany
关键词
asymmetric synthesis; iminations; metal-free; sulfoxides; sulfoximines;
D O I
10.1016/j.tetlet.2005.09.070
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Using a nitrogen transfer agent obtained in situ by mixing of NsNH(2) and PhI(OAc)(2), various N-nosyl sulfoximines and N-nosyl sulfilimines have been prepared under metal-free conditions starting from the corresponding sulfoxides and sulfides, respectively. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:8007 / 8008
页数:2
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