In situ IR, NMR, EPR, and UV/Vis spectroscopy: Tools for new insight into the mechanisms of heterogeneous catalysis

被引：2
作者：
Hunger, M [1 ]
Weitkamp, J [1 ]
机构：
[1] Univ Stuttgart, Inst Tech Chem, D-70550 Stuttgart, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2001年 / 40卷 / 16期
关键词：
active centers; heterogeneous catalysis; in situ spectroscopy; reaction mechanisms; solid catalysts;
D O I：
10.1002/1521-3773(20010817)40:16<2954::AID-ANIE2954>3.0.CO;2-#
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
引用
收藏
页码：2954 / 2971
页数：18
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共 204 条
[11]   Hydrogen exchange between sulfated zirconias and per deutero-benzene as characterization of the surface acidity - Study by DRIFT and H-1 MAS-NMR spectroscopies [J].
Armendariz, H ;
Sierra, CS ;
Figueras, F ;
Coq, B ;
Mirodatos, C ;
Lefebvre, F ;
Tichit, D .
JOURNAL OF CATALYSIS, 1997, 171 (01) :85-92
[12]   C-13 NMR IDENTIFICATION OF INTERMEDIATES FORMED BY 2-METHYL-2-PROPANOL ADSORPTION IN H-ZSM-5 [J].
ARONSON, MT ;
GORTE, RJ ;
FARNETH, WE ;
WHITE, D .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (03) :840-846
[13]   In situ IR spectroscopic study of the adsorption behaviour of ethylbenzene and diethylbenzenes related to ethylbenzene disproportionation over HY zeolite [J].
Arsenova, N ;
Bludau, H ;
Haag, W ;
Karge, HG .
MICROPOROUS AND MESOPOROUS MATERIALS, 1998, 23 (1-2) :1-10
[14]   An infrared study of NO decomposition over Cu-ZSM-5 [J].
Aylor, AW ;
Larsen, SC ;
Reimer, JA ;
Bell, AT .
JOURNAL OF CATALYSIS, 1995, 157 (02) :592-602
[15]   N-alkylnitrilium cations in zeolites:: A study using theoretical chemistry and in situ NMR with the pulse-quench reactor [J].
Barich, DH ;
Xu, T ;
Song, WG ;
Wang, ZK ;
Deng, F ;
Haw, JF .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (37) :7163-7168
[16]   ELIMINATION AND ION MOLECULE REACTIONS OF HEXAMETHYLETHANE AND TRIMETHYLBUTANE RADICAL CATIONS IN ZSM-5 [J].
BARNABAS, MV ;
WERST, DW ;
TRIFUNAC, AD .
CHEMICAL PHYSICS LETTERS, 1993, 204 (5-6) :435-439
[17]   QUADRICYCLANE AND NORBORNADIENE RADICAL CATIONS IN SILICALITE - COMPARISON WITH FREON MATRICES [J].
BARNABAS, MV ;
WERST, DW ;
TRIFUNAC, AD .
CHEMICAL PHYSICS LETTERS, 1993, 206 (1-4) :21-24
[18]   KINETIC NMR AND DENSITY-FUNCTIONAL STUDY OF BENZENE H/D EXCHANGE IN ZEOLITES, THE MOST SIMPLE AROMATIC-SUBSTITUTION [J].
BECK, LW ;
XU, T ;
NICHOLAS, JB ;
HAW, JF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (46) :11594-11595
[19]   A PROBE OF BRONSTED SITE ACIDITY IN ZEOLITES - C-13 CHEMICAL-SHIFT OF ACETONE [J].
BIAGLOW, AI ;
GORTE, RJ ;
KOKOTAILO, GT ;
WHITE, D .
JOURNAL OF CATALYSIS, 1994, 148 (02) :779-786
[20]   EPR and ENDOR studies of NOx and Cu2+ in zeolites:: bonding and diffusion [J].
Biglino, D ;
Li, HT ;
Erickson, R ;
Lund, A ;
Yahiro, H ;
Shiotani, M .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1999, 1 (12) :2887-2896
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