Photoluminescence and Raman studies of curium and americium complexes of 6-methyl 2-(2-pyridyl)-benzimidazole: Evidence for an efficient intramolecular energy transfer

被引：12

作者：

Assefa, Z

Yaita, T

Haire, RG

Tachimori, S

机构：

[1] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA

[2] Japan Atom Energy Res Inst, Dept Mat Sci, Tokai, Ibaraki 31911, Japan

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 23期

关键词：

D O I：

10.1021/ic034759y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 6-methyl-2-(2-pyridyl)-benzimidazoie (biz) ligand coordinates with the actinide species in solution, and the complexes display efficient intramolecular energy-transfer processes. The energy transfer in the Cm(III)-biz system proceeds in a nonradiative mode, whereas a radiative mode is the principal mechanism in the Am(III)-biz system.

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页码：7375 / 7377

页数：3

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