Tuning of catalytic CO oxidation by changing composition of Rh-Pt bimetallic nanoparticles

被引：187

作者：

Park, Jeong Young ^{[1
,2
]}

Zhang, Yawen ^{[1
,2
,3
,4
]}

Grass, Michael ^{[1
,2
]}

Zhang, Tianfu ^{[1
,2
]}

Somorjai, Gabor A. ^{[1
,2
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Chem & Mat Sci, Berkeley, CA 94720 USA

[3] Peking Univ, PKU HKU Joint Lab Rare Eart Mat & Bioinorgan Chem, Beijing 100871, Peoples R China

[4] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China

来源：

NANO LETTERS | 2008年 / 8卷 / 02期

关键词：

D O I：

10.1021/nl073195i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recent breakthroughs in synthesis in nanoscience have achieved control of size and composition of nanoparticles that are relevant for catalyst design. Here, we show that the catalytic activity of CO oxidation by Rh/Pt bimetallic nanoparticles can be changed by varying the composition at a constant size (9 +/- 1 nm). Two-dimensional Rh/Pt bimetallic nanoparticle arrays were formed on a silicon surface via the Langmuir-Blodgett technique. Composition analysis with X-ray photoelectron spectroscopy agrees with the reaction stoichiometry of Rh/(Pt + Rh). CO oxidation rates that exhibit a 20-fold increase from pure Pt to pure Rh show a nonlinear increase with surface composition of the bimetallic nanoparticles that is consistent with the surface segregation of Pt. The results demonstrate the possibility of controlling catalytic activity in metal nanoparticle-oxide systems via tuning the composition of nanoparticles with potential applications for nanoscale design of industrial catalysts.

引用

页码：673 / 677

页数：5

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