Structural insights into three novel Cu(II), Ni(II) and Zn(II) complexes derived of a pyridine-containing N4-cavity bisoxime ligand

被引：38
作者：
Sun, Yin-Xia [1 ]
Zhang, Wen-Ze [1 ]
Li, Juan [1 ]
Zhang, Yang [1 ]
Dong, Wen-Kui [1 ]
机构：
[1] Lanzhou Jiaotong Univ, Sch Chem & Chem Engn, Lanzhou 730070, Gansu, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2022年 / 531卷
关键词：
N-4-cavity bisoxime ligand; Crystal structure; Synthesis; Complex; Hirshfeld surface analysis; HIRSHFELD ANALYSES; NICKEL(II); MANGANESE(II); COPPER(II); SURFACES;
D O I：
10.1016/j.ica.2021.120723
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three novel N-4-cavity Cu(II), Ni(II) and Zn(II) mononuclear complexes, [Cu(L)(NO3)(2)][Cu(L)(NO3)]NO3 (1) [Ni (T)(NO3)(2)] (2) and [Zn(L)(NO3)(2)] (3) were successfully synthesized via the reactions of a pyridine-containing N-4-cavity bisoxime ligand L (L = 2,2'-[Ethylenedioxobis(azetidinyl)]pyridine) with Cu(II), Ni(II) and Zn(II) nitrates, respectively. Complexes 1-3 were characterized via elemental analysis, IR, UV-Vis spectra and X-ray crystallography. All three complexes are monoclinic systems, containing one M(II) atom and one (L) ligand moiety. Complexes 2 and 3 form centrosymmetric molecules. In addition, supramolecular interactions, Hirshfeld surface analysis were used to analyze the crystal properties that have been studied.
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页数：8
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