Surface transformation and photoinduced recovery in CdSe nanocrystals

被引:98
|
作者
Hess, BC [1 ]
Okhrimenko, IG [1 ]
Davis, RC [1 ]
Stevens, BC [1 ]
Schulzke, QA [1 ]
Wright, KC [1 ]
Bass, CD [1 ]
Evans, CD [1 ]
Summers, SL [1 ]
机构
[1] Brigham Young Univ, Dept Phys & Astron, Provo, UT 84062 USA
关键词
D O I
10.1103/PhysRevLett.86.3132
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
CdSe nanocrystals in solution and films can enter a metastable state in which the highly luminescent nanocrystals become dark. This change, which we attribute to a surface transformation, can be caused by heating or by changing the environment of the nanocrystals at room temperature. The metastable transformation is reversed upon illumination of above-band-gap light, at which point the nanocrystals are again highly luminescent.
引用
收藏
页码:3132 / 3135
页数:4
相关论文
共 50 条
  • [1] Surface stoichiometry of CdSe nanocrystals
    Taylor, J
    Kippeny, T
    Bennett, JC
    Huang, MB
    Feldman, LC
    Rosenthal, SJ
    MICROCRYSTALLINE AND NANOCRYSTALLINE SEMICONDUCTORS-1998, 1999, 536 : 413 - 418
  • [2] Surface relaxation in CdSe nanocrystals
    Leung, K
    Whaley, KB
    JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (22): : 11012 - 11022
  • [3] Photoinduced electron transfer in CdSe nanocrystals passivated by quinone derivatives
    Yarovoi, Alexander A.
    Zenkevich, Eduard I.
    Sagun, Evgenii I.
    Knyukshto, Valentin N.
    Shulga, Alexander M.
    Stupak, Alexander P.
    Dubovskii, Vitaly L.
    ICONO 2007: NOVEL PHOTONICS MATERIALS; OPTICS AND OPTICAL DIAGNOSTICS OF NANOSTRUCTURES, 2007, 6728
  • [4] Photoinduced electron transfer from conjugated polymers to CdSe nanocrystals
    Ginger, DS
    Greenham, NC
    PHYSICAL REVIEW B, 1999, 59 (16) : 10622 - 10629
  • [5] Interplay between optical gain and photoinduced absorption in CdSe nanocrystals
    Malko, AV
    Mikhailovsky, AA
    Petruska, MA
    Hollingsworth, JA
    Klimov, VI
    JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (17): : 5250 - 5255
  • [6] Mechanisms of the wurtzite to rocksalt transformation in CdSe nanocrystals
    Gruenwald, Michael
    Rabani, Eran
    Dellago, Christoph
    PHYSICAL REVIEW LETTERS, 2006, 96 (25)
  • [7] CdSe Semiconductor Nanocrystals: The Surface and the Core
    Blanc, Frederic
    ACS CENTRAL SCIENCE, 2018, 4 (09) : 1081 - 1083
  • [8] The "Surface Optical" Phonon in CdSe Nanocrystals
    Lin, Chen
    Kelley, David F.
    Rico, Mikaela
    Kelley, Anne Myers
    ACS NANO, 2014, 8 (04) : 3928 - 3938
  • [9] "Surface optical" phonons in CdSe nanocrystals
    Kelley, Anne Myers
    Lin, Chen
    Rico, Mikaela
    Kelley, David F.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [10] Ligand dynamics on the surface of CdSe nanocrystals
    Cosseddu, Salvatore
    Pascazio, Roberta
    Giansante, Carlo
    Manna, Liberato
    Infante, Ivan
    NANOSCALE, 2023, 15 (16) : 7410 - 7419