Copper-Catalyzed Direct Carboxylation of C-H Bonds with Carbon Dioxide

被引：303

作者：

Zhang, Liang ^{[1
,2
]}

Cheng, Jianhua ^{[1
,2
]}

Ohishi, Takeshi ^{[1
,2
]}

Hou, Zhaomin ^{[1
,2
]}

机构：

[1] RIKEN Adv Sci Inst, Organometall Chem Lab, Wako, Saitama 3510198, Japan

[2] RIKEN Adv Sci Inst, Adv Catalyst Res Team, Wako, Saitama 3510198, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 46期

基金：

日本学术振兴会;

关键词：

carbene ligands; carbon dioxide; carboxylation; C-H activation; copper catalysts; DIRECT ALKYNYLATION; DIRECT ARYLATION; DIRECT AMINATION; ARYL BROMIDES; CO2; PALLADIUM; REDUCTION; COMPLEXES; DISCOVERY; REAGENTS;

D O I：

10.1002/anie.201003995

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cooking with gas: Copper complexes serve as excellent catalysts for the direct carboxylation of aromatic heterocyclic C-H bonds with CO2, thereby offering an economical and environmentally benign process for the synthesis of heterocyclic carboxylic esters (see scheme; IPr=1,3-bis(2,6- diisopropylphenyl)imidazol-2-ylidene). Some active intermediates of this reaction have been isolated and structurally characterized. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8670 / 8673

页数：4

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