X-ray photoelectron Fe3s and Fe3p spectra of polynuclear trimethylacetate iron complexes

被引：14

作者：

Kochur, A. G. ^{[1
]}

Ivanova, T. M. ^{[2
]}

Shchukarev, A. V. ^{[3
]}

Linko, R. V. ^{[4
]}

Sidorov, A. A. ^{[2
]}

Kiskin, M. A. ^{[2
]}

Novotortsev, V. M. ^{[2
]}

Eremenko, I. L. ^{[2
]}

机构：

[1] Rostov State Univ Transport Commun, Rostov Na Donu 344038, Russia

[2] RAS, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 11999, Russia

[3] Umea Univ, Dept Chem, S-90187 Umea, Sweden

[4] Peoples Friendship Univ, Moscow 117198, Russia

来源：

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 2010年 / 180卷 / 1-3期

基金：

俄罗斯基础研究基金会;

关键词：

XPS; Iron polynuclear complexes; Magnetic properties; PHOTOEMISSION SPECTRA; MULTIPLET STRUCTURE; SPLITTINGS; MN;

D O I：

10.1016/j.elspec.2010.03.011

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

X-ray photoelectron Fe3s and Fe3p spectra are employed to study the electron structure and the spin magnetic state of bi-, tri-, and hexa-nuclear trimethylacetate iron complexes. Assignment of the spectra is performed based on an isolated-ion Pauli-Fock calculation of Fe3s and Fe3p spectra of the Fe atoms in bi- and tri-valent states. Nonequivalent Fe(III) and Fe(II) atoms are detected in tri- and hexa-nuclear complexes. Paramagnetic-limit molecular magnetic moments are calculated using effective atomic magnetic moments obtained from spin-sensitive spectral characteristics. Comparison of those values with the magnetic measurements data demonstrates antiferromagnetic interaction within the complexes. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：21 / 26

页数：6

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