Enantioselective henry reactions catalyzed by chiral N-metal complexes containing R(+)/S(-)-α-ethylphenyl amines

被引:17
作者
Luo, Mei [1 ]
Yan, Bing [2 ,3 ]
机构
[1] Hefei Univ Technol, Hefei 230009, Anhui, Peoples R China
[2] St Jude Childrens Res Hosp, Memphis, TN 38105 USA
[3] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
基金
美国国家科学基金会;
关键词
DIELS-ALDER REACTIONS; NITROALDOL REACTION; COPPER-COMPLEXES; N; N'-DIOXIDE-COPPER(I); COMPLEXES; CYCLOPROPANATION REACTIONS; ALDOL REACTION; LIGANDS; ZN; CU(II);
D O I
10.1016/j.tetlet.2010.08.055
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A series of novel N-metal complexes containing chiral alpha-ethylphenyl amines was synthesized and they catalyzed asymmetric Henry reactions affording products with high enantioselectivity. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5577 / 5580
页数:4
相关论文
共 55 条
[1]  
Adrián F, 1999, EUR J INORG CHEM, P2347
[2]   Copper and manganese complexes with C2-multitopic ligands.: X-ray crystal structure of [Cu(N,N′bis[(S)-prolyl]phenylenediamine)H2O].: Catalytic properties [J].
Alcón, MJ ;
Iglesias, M ;
Sánchez, F .
INORGANICA CHIMICA ACTA, 2002, 333 (01) :83-92
[3]  
[Anonymous], ANGEW CHEM
[4]   Self-assembly of heterobimetallic complexes and reactive nucleophiles: A general strategy for the activation of asymmetric reactions promoted by heterobimetallic catalysts [J].
Arai, T ;
Yamada, YMA ;
Yamamoto, N ;
Sasai, H ;
Shibasaki, M .
CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (11) :1368-1372
[5]   New copper(I) and silver(I) triazolato-complexes: Synthesis, reactivity and catalytic activity in olefin cyclopropanation [J].
Ardizzoia, G. Attilio ;
Brenna, Stefano ;
Castelli, Fulvio ;
Galli, Simona ;
Marelli, Chiara ;
Maspero, Angelo .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2008, 693 (10) :1870-1876
[6]  
ASAI H, 1992, J AM CHEM SOC, V114, P4418
[7]   Recoverable PEG-supported copper catalyst for highly stereocontrolled nitroaldol condensation [J].
Bandini, Marco ;
Benaglia, Maurizio ;
Sinisi, Riccardo ;
Tommasi, Simona ;
Umani-Ronchi, Achille .
ORGANIC LETTERS, 2007, 9 (11) :2151-2153
[8]   Highly enantioselective hetero Diels-Alder reactions of N-sulfinyl dienophiles promoted by copper(II)- and zinc(II)-chiral bis(oxazoline) complexes [J].
Bayer, A ;
Gautun, OR .
TETRAHEDRON-ASYMMETRY, 2001, 12 (21) :2937-2939
[9]  
BLAY G, 2007, TETRAHEDRON-ASYMMETR, V1603, P18
[10]   Modular iminopyridine ligands.: Application to the enantioselective copper(II)-catalyzed Henry reaction [J].
Blay, Gonzalo ;
Climent, Estela ;
Fernandez, Isabel ;
Hernandez-Olmos, Victor ;
Pedro, Jose R. .
TETRAHEDRON-ASYMMETRY, 2006, 17 (14) :2046-2049