Self-assembled nanocotton-like Co-B-P/bacterial cellulose based carbon nanofiber as highly efficient electrocatalyst for oxygen evolution reaction

被引:13
|
作者
Wang, Xuejiao [1 ]
He, Qihang [1 ]
Ge, Qianao [1 ]
Fu, Tongxing [1 ]
Chen, Shouxian [1 ]
Zhou, Pengcheng [1 ]
Xiao, Feng [1 ]
He, Ping [1 ,2 ]
Jia, Lingpu [1 ]
Jia, Bin [2 ,3 ]
Zhang, Hui [2 ,4 ]
Pan, Kai [5 ]
Liu, Hongtao [6 ]
机构
[1] Southwest Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Environm Friendly Energy Mat, Mianyang 621010, Sichuan, Peoples R China
[2] Int Sci & Technol Cooperat Lab Micronanoparticle, Mianyang 621010, Sichuan, Peoples R China
[3] Southwest Univ Sci & Technol, Key Lab Shock & Vibrat Engn Mat & Struct Sichuan, Mianyang 621010, Sichuan, Peoples R China
[4] Western Univ, Dept Chem & Biochem Engn, London, ON N6A 5B9, Canada
[5] Heilongjiang Univ, Key Lab Funct Inorgan Mat Chem, Minist Educ, Harbin 150080, Peoples R China
[6] Cent South Univ, Coll Chem & Chem Engn, Hunan Prov Key Lab Chem Power Sources, Changsha 410083, Peoples R China
基金
国家重点研发计划;
关键词
Oxygen evolution reaction; Electrocatalyst; Bacterial cellulose; Carbon nanofiber; Co-B-P; REDUCED GRAPHENE OXIDE; BACTERIAL-CELLULOSE; ACTIVE ELECTROCATALYST; BIFUNCTIONAL ELECTROCATALYST; NICKEL BORIDE; HYDROGEN; NI; NANOPARTICLES; CATALYST; NANOSHEETS;
D O I
10.1016/j.ijhydene.2021.03.211
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
It is urgent and challenging to exploit highly efficient oxygen evolution reaction (OER) catalysts for water splitting. Bacterial cellulose based carbon nanofiber (BCCNF) is high-lighted for its 3D network structure, abundant surface functional groups and good & nbsp;conductivity. Herein, based on the different molar ratio of P/B precursor, a series of nanocotton-like Co-B-P/BCCNF electrocatalysts have been designed and prepared via a simple electroless deposition. When the molar ratio of P/B precursor is 3/7, nanocotton-like Co-B-P/BCCNF catalyst exhibits prominent catalytic performances, delivering the current density of 10 and 50 mA cm-2 at low overpotentials of only 262 and 391 mV, respectively. Besides, it exhibits long-term stability for durative OER in alkaline solution. This result indicates that nanocotton-like Co-B-P/BCCNF catalyst has great potential as OER catalysts for large-scale hydrogen production via water splitting. (c) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:20930 / 20940
页数:11
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