Thermal conductivity and dielectric properties of bismaleimide/cyanate ester copolymer

被引:40
作者
Wan, Lin [1 ]
Zhang, Xia [1 ]
Wu, Guanglei [2 ]
Feng, Ailing [3 ]
机构
[1] Ocean Univ China, Coll Chem & Chem Engn, Key Lab Marine Chem Theory & Technol, Minist Educ, Qingdao 266100, Peoples R China
[2] Qingdao Univ, Inst Energy & Environm Mat, Coll Mat Sci & Engn, Qingdao 266071, Peoples R China
[3] Baoji Univ Arts & Sci, Inst Phys & Optoelect Technol, Baoji 721016, Peoples R China
来源
HIGH VOLTAGE | 2017年 / 2卷 / 03期
基金
中国博士后科学基金;
关键词
POLYHEDRAL OLIGOMERIC SILSESQUIOXANE; BORON-NITRIDE; RAFT POLYMERIZATION; EPOXY COMPOSITES; NANOCOMPOSITES; RESIN; CONSTANT; DENSITY; FIBERS; FILLER;
D O I
10.1049/hve.2017.0056
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
The blend was synthesised with bismaleimide (BMI) resin and bisphenol A-based cyanate ester (BADCy) resin. The BMI/BADCy copolymer showed excellent dielectric and thermal conductivity properties. The volume resistivity of the copolymer was a little lower than BADCy system. The volume resistivity of blend was 7.8x10(15<bold>)cm when the BMI content was </bold>20wt%, which still showed good insulation performance. The dielectric property of modified BADCy copolymer remained the good stability from 0.1Hz to 1MHz. Compared to pure BADCy system, the breakdown property of BMI/BADCy blend reached the maximum value of 77.9kV/mm when the content of BMI was 20wt%, which was still about 1.22 times. The thermal property and thermal conductivity property of the copolymer were higher than BADCy system.
引用
收藏
页码:167 / 171
页数:5
相关论文
共 26 条
[1]   A study of encapsulation resin containing hexagonal boron nitride (hBN) as inorganic filler [J].
Chiang, Tzu Hsuan ;
Hsieh, T. -E. .
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2006, 16 (02) :175-183
[2]   Examining the thermo-mechanical properties of novel cyanate ester blends through empirical measurement and simulation [J].
Crawford, Alasdair O. ;
Howlin, Brendan J. ;
Cavalli, Gabriel ;
Hamerton, Ian .
REACTIVE & FUNCTIONAL POLYMERS, 2012, 72 (09) :596-605
[3]   1D/2D Carbon Nanomaterial-Polymer Dielectric Composites with High Permittivity for Power Energy Storage Applications [J].
Dang, Zhi-Min ;
Zheng, Ming-Sheng ;
Zha, Jun-Wei .
SMALL, 2016, 12 (13) :1688-1701
[4]   Thermal and mechanical evaluation of cyanate ester composites with low-temperature processability [J].
Goertzen, W. K. ;
Kessler, M. R. .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2007, 38 (03) :779-784
[5]   Ideal dielectric thermally conductive bismaleimide nanocomposites filled with polyhedral oligomeric silsesquioxane functionalized nanosized boron nitride [J].
Gu, Junwei ;
Liang, Chaobo ;
Dang, Jing ;
Dong, Wencai ;
Zhang, Qiuyu .
RSC ADVANCES, 2016, 6 (42) :35809-35814
[6]   Functionalized graphite nanoplatelets/epoxy resin nanocomposites with high thermal conductivity [J].
Gu, Junwei ;
Yang, Xutong ;
Lv, Zhaoyuan ;
Li, Nan ;
Liang, Chaobo ;
Zhang, Qiuyu .
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2016, 92 :15-22
[7]   Polyhedral Oligosilsesquioxane-Modified Boron Nitride Nanotube Based Epoxy Nanocomposites: An Ideal Dielectric Material with High Thermal Conductivity [J].
Huang, Xingyi ;
Zhi, Chunyi ;
Jiang, Pingkai ;
Golberg, Dmitri ;
Bando, Yoshio ;
Tanaka, Toshikatsu .
ADVANCED FUNCTIONAL MATERIALS, 2013, 23 (14) :1824-1831
[8]   A Review of Dielectric Polymer Composites With High Thermal Conductivity [J].
Huang, Xingyi ;
Jiang, Pingkai ;
Tanaka, Toshikatsu .
IEEE ELECTRICAL INSULATION MAGAZINE, 2011, 27 (04) :8-16
[9]   Flexible high-temperature dielectric materials from polymer nanocomposites [J].
Li, Qi ;
Chen, Lei ;
Gadinski, Matthew R. ;
Zhang, Shihai ;
Zhang, Guangzu ;
Li, Haoyu ;
Haque, Aman ;
Chen, Long-Qing ;
Jackson, Thomas N. ;
Wang, Qing .
NATURE, 2015, 523 (7562) :576-+
[10]   A multifunctional silicon-containing hyperbranched epoxy: controlled synthesis, toughening bismaleimide and fluorescent properties [J].
Niu, Song ;
Yan, Hongxia ;
Li, Song ;
Tang, Cheng ;
Chen, Zhengyan ;
Zhi, Xiaoli ;
Xu, Peilun .
JOURNAL OF MATERIALS CHEMISTRY C, 2016, 4 (28) :6881-6893