Recent Advances in Visible-Light-Driven Hydrogen Evolution from Water using Polymer Photocatalysts

被引：122

作者：

Jayakumar, Jayachandran ^{[1
]}

Chou, Ho-Hsiu ^{[1
]}

机构：

[1] Natl Tsing Hua Univ, Dept Chem Engn, 101,Sec 2,Kuang Fu Rd, Hsinchu 30013, Taiwan

来源：

CHEMCATCHEM | 2020年 / 12卷 / 03期

关键词：

AQY; conjugated polymer; hydrogen evolution; polymer dots; porous polymer; triazine frameworks; CONJUGATED MICROPOROUS POLYMERS; COVALENT ORGANIC FRAMEWORK; TRIAZINE-BASED FRAMEWORKS; GRAPHITIC CARBON NITRIDE; HEPTAZINE-BASED POLYMER; H-2; EVOLUTION; ARTIFICIAL PHOTOSYNTHESIS; POROUS POLYMERS; DOTS; DESIGN;

D O I：

10.1002/cctc.201901725

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Efficient polymer photocatalysts that mimic natural photosynthesis to generate H-2 through the visible-light-promoted splitting of water are ideal systems for the conversion of solar energy into usable fuel with high energy density and in an environmentally friendly manner. In this article, we review recent reports on donor-acceptor-based pi-conjugated polymers as photocatalysts, including conjugated linear polymers, microporous polymers, triazine frameworks, covalent organic frameworks, polymer dots, and other related organic polymers, which show superior photocatalytic activity and robust stability under visible-light irradiation, for hydrogen production. Moreover, their syntheses and material design strategies, photophysical properties, proposed mechanisms, and applications are systematically summarized. Finally, recent research on and challenges related to organic polymer photocatalysts are discussed. This minireview will help readers to more easily understand the recent advances in and future direction of this field.

引用

页码：689 / 704

页数：16

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