Bis-sulfoxides as ligands for platinum complexes

被引：7
作者：
Mallorquin, Rocio Martinez [1 ]
Chelli, Saloua [1 ]
Brebion, Franck [1 ]
Fensterbank, Louis [1 ]
Goddard, Jean-Philippe [1 ]
Malacria, Max [1 ]
机构：
[1] Univ Paris 06, UPMC, FR 2769, CNRS,Inst Parisien Chim Mol,UMR 7201, F-75005 Paris, France
来源：
TETRAHEDRON-ASYMMETRY | 2010年 / 21卷 / 13-14期
关键词：
ENANTIOMERICALLY PURE SULFOXIDES; CHIRAL KETENE EQUIVALENT; ASYMMETRIC-SYNTHESIS; CATALYZED CYCLOISOMERIZATION; MOLECULAR-STRUCTURE; CONJUGATE ADDITION; DOMINO REACTIONS; SULFUR LIGANDS; GENERAL-ROUTE; PALLADIUM(II);
D O I：
10.1016/j.tetasy.2010.04.023
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In this article, we describe two new platinum(II) complexes incorporating C(2)-symmetric enantiopure bis-sulfoxides ligands. The originality of these structures resides in the one-carbon tether between the two sulfoxide functions. X-ray structures show that coordination takes place through both sulfur atoms giving birth to intriguing platina-cyclobutane systems. We anticipate that these complexes should find uses in asymmetric catalysis. (C) 2010 Elsevier Ltd. All rights reserved.
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收藏
页码：1695 / 1700
页数：6
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