Application of ultraviolet fluorometry and excitation-emission matrix spectroscopy (EEMS) to fingerprint oil and chemically dispersed oil in seawater

被引：68

作者：

Bugden, J. B. C. ^{[1
]}

Yeung, C. W. ^{[1
]}

Kepkay, P. E. ^{[1
]}

Lee, K. ^{[1
]}

机构：

[1] Fisheries & Oceans Canada, Bedford Inst Oceanog, COOGER, Dartmouth, NS B2Y 4A2, Canada

来源：

MARINE POLLUTION BULLETIN | 2008年 / 56卷 / 04期

关键词：

oil fluorescence; oil fingerprints; EEMS; dispersant; emission ratios;

D O I：

10.1016/j.marpolbul.2007.12.022

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Excitation-emission matrix spectroscopy (EEMS) was used to characterize the ultra violet fluorescence fingerprints of eight crude oils (with a 14,470-fold range of dynamic viscosity) in seawater. When the chemical dispersant Corexit 9500 (R) was mixed with the oils prior to their dispersion in seawater, the fingerprints of each oil changed primarily as an increase in fluorescence over an emission band centered on 445 nm. In order to simplify the wealth of information available in the excitation-emission matrix spectra (EEMs), two ratios were calculated. A 66-90% decrease in the slope ratio was observed with the addition of Corexit. When the slope ratios were reduced in complexity to intensity ratios, similar trends were apparent. As a result either of the ratios could be used as a simple and rapid means of identifying and monitoring chemically dispersed oil in the open ocean. Crown Copyright (c) 2008 Published by Elsevier Ltd. All rights reserved.

引用

页码：677 / 685

页数：9

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