Bis(mesitoyl)phosphinic acid: photo-triggered release of metaphosphorous acid in solution

被引：16

作者：

Fast, David E. ^{[1
]}

Zalibera, Michal ^{[1
,2
]}

Lauer, Andrea ^{[3
,4
]}

Eibel, Anna ^{[1
]}

Schweigert, Caroline ^{[5
]}

Kelterer, Anne-Marie ^{[1
]}

Spichty, Martin ^{[6
]}

Neshchadin, Dmytro ^{[1
]}

Voll, Dominik ^{[3
,4
]}

Ernst, Hanna ^{[5
]}

Liang, Yu ^{[5
]}

Dietliker, Kurt ^{[7
]}

Unterreiner, Andreas-Neil ^{[5
]}

Barner-Kowollik, Christopher ^{[3
,4
]}

Grutzmacher, Hansjorg ^{[7
]}

Gescheidt, Georg ^{[1
]}

机构：

[1] Graz Univ Technol, Inst Phys & Theoret Chem, NAWI Graz, Stremayrgasse 9, A-8010 Graz, Austria

[2] Slovak Univ Technol Bratislava, Inst Phys Chem & Chem Phys, Radlinskeho 9, Bratislava 81227, Slovakia

[3] Karlsruhe Inst Technol, Inst Tech Chem & Polymerchem, Preparat Macromol Chem, Engesserstr 18, D-76128 Karlsruhe, Germany

[4] Karlsruhe Inst Technol, Inst Biol Grenzflachen, Herrmann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany

[5] Karlsruhe Inst Technol, Inst Phys Chem, Fritz Haber Weg 2, D-76131 Karlsruhe, Germany

[6] Ecole Normale Super Lyon, Lab Mol & Cellular Biol Struct & Interact Mol Bio, 46 Allee Italie, F-69364 Lyon 07, France

[7] ETH Swiss Fed Inst Technol, Dept Chem & Appl Biosci, Vladimir Prelog Weg 1, CH-8093 Zurich, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 64期

关键词：

LASER FLASH-PHOTOLYSIS; PHOTOINITIATED RADICAL POLYMERIZATION; IONIZATION MASS-SPECTROMETRY; ELECTRON-SPIN-RESONANCE; ABSOLUTE RATE CONSTANTS; TIME-RESOLVED ESR; OXIDE PHOTOINITIATORS; BENZOYL RADICALS; PHOSPHINOYL; REACTIVITY;

D O I：

10.1039/c6cc05219c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis(mesitoyl)phosphinic acid and its sodium salt display a unique photo induced reactivity: both derivatives stepwise release two mesitoyl radicals and, remarkably, metaphosphorous acid (previously postulated as transient species in the gas phase), providing a new phosphorus based reagent.

引用

页码：9917 / 9920

页数：4

共 30 条

[1] Gel permeation chromatography coupled to Fourier transform mass spectrometry for polymer characterization [J].

Aaserud, DJ ;

Prokai, L ;

Simonsick, WJ .

ANALYTICAL CHEMISTRY, 1999, 71 (21) :4793-4799

[2] Detection of the transient molecule HOPO in the gas phase by infrared laser spectroscopy [J].

Bell, IS ;

Ahmad, IK ;

Hamilton, PA ;

Davies, PB .

CHEMICAL PHYSICS LETTERS, 2000, 320 (3-4) :311-315

[3] Highly Efficient Water-Soluble Visible Light Photoinitiators [J].

Benedikt, Stephan ;

Wang, Jieping ;

Markovic, Marica ;

Moszner, Norbert ;

Dietliker, Kurt ;

Ovsianikov, Aleksandr ;

Gruetzmacher, Hansjoerg ;

Liska, Robert .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2016, 54 (04) :473-479

[4] Probing the reactivity of photoinitiators for free radical polymerization: Time-resolved infrared spectroscopic study of benzoyl radicals [J].

Colley, CS ;

Grills, DC ;

Besley, NA ;

Jockusch, S ;

Matousek, P ;

Parker, AW ;

Towrie, M ;

Turro, NJ ;

Gill, PMW ;

George, MW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (50) :14952-14958

[5] Recent developments in photoinitiated radical polymerization [J].

Decker, C .

MACROMOLECULAR SYMPOSIA, 1999, 143 :45-63

[6] New developments in photoinitiators [J].

Dietliker, K ;

Jung, TJ ;

Benkhoff, J ;

Kura, H ;

Matsumoto, A ;

Oka, H ;

Hristova, D ;

Gescheidt, G ;

Rist, G .

MACROMOLECULAR SYMPOSIA, 2004, 217 :77-97

[7] Studying the polymerization initiation efficiency of acetophenone-type initiators via PLP-ESI-MS and femtosecond spectroscopy [J].

Frick, Elena ;

Ernst, Hanna A. ;

Voll, Dominik ;

Wolf, Thomas J. A. ;

Unterreiner, Andreas-Neil ;

Barner-Kowollik, Christopher .

POLYMER CHEMISTRY, 2014, 5 (17) :5053-5068

[8]

Gallagher M. J., 1991, HDB PHOSPHORUS 31 NU, P287

[9] Fast and Accurate Determination of Absolute Individual Molecular Weight Distributions from Mixtures of Polymers via Size Exclusion Chromatography-Electrospray Ionization Mass Spectrometry [J].

Gruendling, Till ;

Guilhaus, Michael ;

Barner-Kowollik, Christopher .

MACROMOLECULES, 2009, 42 (17) :6366-6374

[10]

Hayashi H., 2004, INTRO DYNAMICS SPIN

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