Mixing enthalpies in liquid alloys of manganese with the lanthanides

被引：37

作者：

Ivanov, Michael ^{[2
]}

Berezutski, Vadim ^{[2
]}

Usenko, Nathalia ^{[1
]}

机构：

[1] Taras Shevchenko Natl Univ, Dept Chem, UA-01601 Kiev, Ukraine

[2] Natl Acad Sci, I Frantsevich Inst Problems Mat Sci, Kiev, Ukraine

来源：

INTERNATIONAL JOURNAL OF MATERIALS RESEARCH | 2011年 / 102卷 / 03期

关键词：

Manganese; Lanthanides; Calorimetry; Enthalpy of mixing; THERMODYNAMIC PROPERTIES; SYSTEMS; THERMOCHEMISTRY; ELEMENTS; METALS; GD;

D O I：

10.3139/146.110474

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

The enthalpies of mixing in binary liquid alloys of manganese with the lanthanides (Nd, Gd, Tb, Dy, Tm and Lu) were determined over a wide range of composition by isoperibolic calorimetry. The heats of mixing in the systems were found to change gradually across the lanthanides row from the Mn-Nd system (Delta H-min = -0.40 +/- 0.26 kJ mol(-1) at x(Nd) = 0.14; Delta H-max = 1.99 +/- 0.65 kJ mol(-1) at x(Nd) = 0.60; T = 1 600 K) to the Mn-Lu system (Delta H-min = -6.76 +/- 0.93 kJ mol(-1) at x(Lu) = 0.40; T = 1 700 K)

引用

页码：277 / 281

页数：5

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