Mixing enthalpies in liquid alloys of manganese with the lanthanides

被引：37

作者：

Ivanov, Michael ^{[2
]}

Berezutski, Vadim ^{[2
]}

Usenko, Nathalia ^{[1
]}

机构：

[1] Taras Shevchenko Natl Univ, Dept Chem, UA-01601 Kiev, Ukraine

[2] Natl Acad Sci, I Frantsevich Inst Problems Mat Sci, Kiev, Ukraine

来源：

INTERNATIONAL JOURNAL OF MATERIALS RESEARCH | 2011年 / 102卷 / 03期

关键词：

Manganese; Lanthanides; Calorimetry; Enthalpy of mixing; THERMODYNAMIC PROPERTIES; SYSTEMS; THERMOCHEMISTRY; ELEMENTS; METALS; GD;

D O I：

10.3139/146.110474

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

The enthalpies of mixing in binary liquid alloys of manganese with the lanthanides (Nd, Gd, Tb, Dy, Tm and Lu) were determined over a wide range of composition by isoperibolic calorimetry. The heats of mixing in the systems were found to change gradually across the lanthanides row from the Mn-Nd system (Delta H-min = -0.40 +/- 0.26 kJ mol(-1) at x(Nd) = 0.14; Delta H-max = 1.99 +/- 0.65 kJ mol(-1) at x(Nd) = 0.60; T = 1 600 K) to the Mn-Lu system (Delta H-min = -6.76 +/- 0.93 kJ mol(-1) at x(Lu) = 0.40; T = 1 700 K)

引用

页码：277 / 281

页数：5

共 19 条

[1] ALCOCK CB, 1984, CAN METALL QUART, V23, P309
[2] MATHEMATICAL REPRESENTATION OF THERMODYNAMIC PROPERTIES IN BINARY-SYSTEMS AND SOLUTION OF GIBBS-DUHEM EQUATION
BALE, CW
PELTON, AD
[J]. METALLURGICAL TRANSACTIONS, 1974, 5 (11): : 2323 - 2337
[3] Mixing enthalpies in samarium-transition metal melts
Berezutskii, V. V.
Ivanov, M. I.
[J]. POWDER METALLURGY AND METAL CERAMICS, 2009, 48 (7-8) : 454 - 461
[4] Boer FRd, 1988, Cohesion in Metals
[5] Computational and experimental study of phase stability, cohesive properties, magnetism and electronic structure of TiMn2
Chen, XQ
Witusiewicz, VT
Podloucky, R
Rogl, P
Sommer, F
[J]. ACTA MATERIALIA, 2003, 51 (05) : 1239 - 1247
[6] THE THERMODYNAMIC PROPERTIES OF RARE-EARTH METALLIC SYSTEMS
COLINET, C
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 225 (1-2) : 409 - 422
[7] SGTE DATA FOR PURE ELEMENTS
DINSDALE, AT
[J]. CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 1991, 15 (04): : 317 - 425
[8] Thermodynamic optimization of the systems Mn-Gd and Mn-Y using new experimental results
Gröbner, J
Pisch, A
Schmid-Fetzer, R
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2001, 317 : 433 - 437
[9] HARRISON WA, 1982, ELECT STRUCTURE PROP
[10] Hultgren R., 1973, Selected Values of Thermodynamic Properties of Elements

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