Reaction of 1-phenylcyclooctene with NBS.: Synthesis of allylic alcohols and 1,3-dienes

被引：0

作者：

Büyükkidan, B ^{[1
]}

Budak, IG ^{[1
]}

Ceylan, M ^{[1
]}

机构：

[1] Gaziosmanpasa Univ, Fac Sci, Dept Chem, TR-60240 Tokat, Turkey

来源：

ACTA CHIMICA SLOVENICA | 2003年 / 50卷 / 03期

关键词：

cyclooctan-1-ylbenzene; NBS; AgClO4; vinyl bromide; 1,3-diene; allyl alcohol;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of 1-phenylcyclooctene (3) with NBS resulted in the formation of a mixture of products (4-8). After column chromatography, we isolated the vinyl bromide 14 and 1,3-dienes 9, 10, bromo-1, 3-dienes 11, 12 and allylic alcohol 15. Reaction of the mixture (4-8) with AgClO4 afforded compounds 9, 14, 15 and alpha, beta-unsaturated ketones 21 and 22.

引用

页码：419 / +

页数：12

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