Oxidation of alcohols with benzyltripenylphophonium peroxymonosulfate under non-aqueous conditions

被引：15
作者：
Hajipour, AR [1 ]
Mallakpour, SE [1 ]
Adibi, H [1 ]
机构：
[1] Isfahan Univ Technol, Coll Chem, Pharmaceut Res Lab, Esfahan 84156, Iran
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2000年 / 167卷
关键词：
alcohols; benzyltriphenylphosphonium peroxymonosulfate; bismuth chloride; oxidation; potassium peroxymonosulfate (Oxone (R));
D O I：
10.1080/10426500008082388
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Oxidation of allylic and benzylic alcohols with benzyltriphenylphosphonium peroxymonosulfate (PhCH2Ph3P+HSO5-) 1 (BTPPMS) in refluxing acetonitrile is reported. The oxidation in the presence of a catalytic amount of bismuth chloride enhances the rate.
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页码：71 / 79
页数：9
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