Tandem transition metal catalyzed isomerization and cationic polymerization

被引:4
作者
Crivello, JV [1 ]
Rajaraman, SK [1 ]
机构
[1] Rensselaer Polytech Inst, Dept Chem, Troy, NY 12180 USA
关键词
D O I
10.1002/masy.19981320106
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A wide variety of mono-, di- and multifunctional allyl ethers and related compounds are readily polymerized using a newly discovered polymerization reaction which has been termed: a transition metal-catalyzed tandem isomerization and cationic polymerization. Employing dicobalt octacarbonyl in combination with organosilanes, the polymerization of these monomers takes place rapidly to give high molecular weight polymers.
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页码:37 / 43
页数:7
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