Synthesis of perfluorinated allylic compounds by radical allylation and their purification over fluorous reverse-phase silica

被引：35

作者：

Ryu, IY ^{[1
]}

Kreimerman, S

Niguma, T

Minakata, S

Komatsu, M

Luo, ZY

Curran, DP

机构：

[1] Osaka Prefecture Univ, Fac Arts & Sci, Dept Chem, Sakai, Osaka 5998531, Japan

[2] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

[3] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA

[4] Univ Pittsburgh, Ctr Combinatorial Chem, Pittsburgh, PA 15260 USA

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 05期

基金：

美国国家科学基金会; 日本学术振兴会;

关键词：

D O I：

10.1016/S0040-4039(00)02153-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple free-radical method for the preparation of a variety of perfluorinated allylic compounds has been developed starting from perfluoroalkyl iodides and allyltins. Allyltributyltin, methallyltributyltin and crotyltributyltin all proved to be useful For the transformation. The desired perfluorinated allylic compound was conveniently isolated from the crude mixture by solid-phase extraction with fluorous reverse-phase silica (FRPS). (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：947 / 950

页数：4

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