Metal-Free Ring-Opening Polymerization of Glycidyl Phenyl Ether Initiated by Tetra-n-butylammonium Acetate and Its Application to the Hydroxyl-Terminated Telechelic Polymer

被引：12

作者：

Morinaga, Hisatoyo ^{[1
]}

Ujihara, Yusuke ^{[1
,2
]}

Yamanaka, Takahiro ^{[1
]}

Nagai, Daisuke ^{[3
]}

Endo, Takeshi ^{[4
]}

机构：

[1] Kochi Natl Coll Technol, Dept Mat Sci & Engn, Nanko Ku, Kochi 7838508, Japan

[2] Kochi Natl Coll Technol, Adv Course Mat Sci & Engn, Nanko Ku, Kochi 7838508, Japan

[3] Gunma Univ, Grad Sch Engn, Dept Chem & Chem Biol, Gunma 3768515, Japan

[4] Kinki Univ, Mol Engn Inst, Fukuoka 8208555, Japan

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2011年 / 49卷 / 18期

关键词：

anionic polymerization; epoxides; metal-free polymerization; ring-opening polymerization; telechelics; ANIONIC-POLYMERIZATION; COPOLYMERIZATION BEHAVIOR; CATALYZED POLYMERIZATION; CYCLIC CARBONATES; BLOCK-COPOLYMERS; EPOXIDES;

D O I：

10.1002/pola.24833

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A ring-opening polymerization of glycidyl phenyl ether (GPE) was performed with a metal-free tetra-n-butylammonium acetate (Bu4NOAc). The polymerization of GPE initiated by Bu4NOAc enables to control the molecular weight of poly(GPE). This metal-free GPE polymerization system with Bu4NOAc is useful, because the hydroxyl terminated telechelic polymer with narrow molecular weight distribution is facilely obtained. © 2011 Wiley Periodicals, Inc.

引用

页码：4092 / 4097

页数：6

共 7 条

[1] Controlled Polymerization of Epoxides: Metal-Free Ring-Opening Polymerization of Glycidyl Phenyl Ether Initiated by Tetra-n-butylammonium Fluoride in the Presence of Protic Compounds
Morinaga, Hisatoyo
Ujihara, Yusuke
Yuto, Naho
Nagai, Daisuke
Endo, Takeshi
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2011, 49 (24) : 5210 - 5216
[2] Metal-free ring-opening block copolymerization of glycidyl phenyl ether with trimethylene carbonate initiated by tetra-n-butylammonium fluoride
Morinaga, Hisatoyo
Ujihara, Yusuke
Endo, Takeshi
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2012, 50 (16) : 3461 - 3465
[3] Metal-free synthesis of reactive oligomers by ring-opening oligomerization of glycidyl phenyl ether initiated with tetra-n-butylammonium fluoride in the presence of various protic compounds
Morinaga, Hisatoyo
Tsuneishi, Fumiya
Taniguchi, Seiya
Kawakami, Genta
TETRAHEDRON LETTERS, 2014, 55 (28) : 3768 - 3770
[4] Synthesis of Amphiphilic Block Copolymer by Metal-Free Ring-Opening Oligomerization of Glycidyl phenyl ether Initiated with Tetra-n-butylammonium fluoride in the Presence of Poly(ethylene glycol) monomethyl ether
Morinaga, Hisatoyo
Ujihara, Yusuke
Endo, Takeshi
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2013, 51 (20) : 4451 - 4458
[5] Metal-free ring-opening polymerization of glycidyl phenyl ether by tetrabutylammonium fluoride
Morinaga, Hisatoyo
Ochiai, Bungo
Endo, Takeshi
MACROMOLECULES, 2007, 40 (16) : 6014 - 6016
[6] A Facile Synthesis of Branched Oligomers by Metal-free Ring-opening Oligomerization of Glycidyl Phenyl Ether Initiated with n-Bu4NF in the Presence of Polyhydric Alcohols
Morinaga, Hisatoyo
Taniguchi, Seiya
CHEMISTRY LETTERS, 2015, 44 (08) : 1145 - 1147
[7] Organocatalytic Ring-Opening Polymerization of ε-Caprolactone Using bis(N-(N′-butylimidazolium)alkane Dicationic Ionic Liquids as the Metal-Free Catalysts: Polymer Synthesis, Kinetics and DFT Mechanistic Study
Cheechana, Nathaporn
Benchaphanthawee, Wachara
Akkravijitkul, Natthapol
Rithchumpon, Puracheth
Junpirom, Thiti
Limwanich, Wanich
Punyodom, Winita
Kungwan, Nawee
Ngaojampa, Chanisorn
Thavornyutikarn, Praput
Meepowpan, Puttinan
POLYMERS, 2021, 13 (24)

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