Templated Synthesis, Postsynthetic Metal Exchange, and Properties of a Porphyrin-Encapsulating Metal-Organic Material

被引：214

作者：

Zhang, Zhenjie ^{[1
]}

Zhang, Linping ^{[1
]}

Wojtas, Lukasz ^{[1
]}

Nugent, Patrick ^{[1
]}

Eddaoudi, Mohamed ^{[1
,2
]}

Zaworotko, Michael J. ^{[1
]}

机构：

[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

[2] 4700 King Abdullah Univ Sci & Technol, Thuwal 239556900, Saudi Arabia

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 02期

关键词：

HYDROGEN ADSORPTION; SINGLE-CRYSTAL; FRAMEWORKS; COMPLEXES; LINKING; STORAGE; UNITS;

D O I：

10.1021/ja209643b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of biphenyl-3,4',5-tricarboxylate (H3BPT) and CdCl2 in the presence of meso-tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) afforded porph@MOM-10, a microporous metal-organic material containing CdTMPyP cations encapsulated in an anionic Cd(II) carboxylate framework, [Cd-6(BPT)(4)Cl-4(H2O)(4)]. Porph@MOM-10 is a versatile platform that undergoes exchange to serve as the parent of a series of porph@MOMs that exhibit permanent porosity and heterogeneous catalytic activity.

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收藏

页码：924 / 927

页数：4

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