Highly stereoselective reduction of 4-Aryl-2-oxo but-3-enoic carboxylic esters by plant cell culture of Daucus carota

被引：40
作者：
Baskar, B
Ganesh, S
Lokeswari, TS
Chadha, A [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India
[2] SPIC Sci Fdn, Div Biotechnol, Madras 600032, Tamil Nadu, India
来源：
JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC | 2004年 / 27卷 / 01期
关键词：
Daucus carota; plant tissue culture; asymmetric reduction; alpha-hydroxy beta; gamma-unsaturated arylidine esters;
D O I：
10.1016/j.molcatb.2003.09.004
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
A highly enantioselective preparation (92-99% enantiomeric excess, 100% conversion) of various 4-aryl-2-hydroxy but-3-enoic carboxylic acid esters from the corresponding 4-phenyl-2-keto but-3-enoic acid esters mediated by plant cell cultures of Daucus carota under mild and environmentally benign conditions in aqueous medium is described. (C) 2003 Elsevier B.V All rights reserved.
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收藏
页码：13 / 17
页数：5
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