Ultra-strong coupling of molecular materials: spectroscopy and dynamics

被引:104
作者
George, Jino
Wang, Shaojun
Chervy, Thibault
Canaguier-Durand, Antoine
Schaeffer, Gael
Lehn, Jean-Marie
Hutchison, James A. [1 ]
Genet, Cyriaque
Ebbesen, Thomas W.
机构
[1] Univ Strasbourg, ISIS, F-67000 Strasbourg, France
关键词
RABI OSCILLATIONS; CAVITY; EXCITONS; PLASMONS; REGIME; ATOM;
D O I
10.1039/c4fd00197d
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report here a study of light-matter strong coupling involving three molecules with very different photo-physical properties. In particular we analyze their emission properties and show that the excitation spectra are very different from the static absorption of the coupled systems. Furthermore we report the emission quantum yields and excited state lifetimes, which are self-consistent. The above results raise a number of fundamental questions that are discussed and these demonstrate the need for further experiments and theoretical studies.
引用
收藏
页码:281 / 294
页数:14
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