Water transport in an epoxy-phenolic coating

被引：45
作者：
Morsch, S. [1 ]
Lyon, S. [1 ]
Greensmith, P. [2 ]
Smith, S. D. [3 ]
Gibbon, S. R. [4 ]
机构：
[1] Univ Manchester, Sch Mat, Ctr Corros & Protect, Manchester M13 9PL, Lancs, England
[2] Univ Manchester, Sch Mat, Ctr Mat Sci, Manchester M13 9PL, Lancs, England
[3] Akzo Nobel Chem BV, NL-7400 AA Deventer, Netherlands
[4] Mao Nobel Supply Chain, Gateshead NE10 0JY, Tyne & Wear, England
来源：
PROGRESS IN ORGANIC COATINGS | 2015年 / 78卷
关键词：
Epoxy-phenolic; Water uptake; Infrared spectroscopy; FREE-VOLUME; MOLECULAR-INTERACTIONS; CORROSION PROTECTION; THERMAL-DEGRADATION; MOISTURE TRANSPORT; NANOVOID STRUCTURE; GLASS-TRANSITION; RESIN; ABSORPTION; DIFFUSION;
D O I：
10.1016/j.porgcoat.2014.08.006
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Thermoset coatings commonly rely on high cross-linking density to provide enhanced barrier properties. Hence it is surprising that for the industrial epoxy phenolic network investigated, equilibrium moisture uptake is found to increase with respect to cure time, i.e., with greater cross-linking. Molecular interactions between absorbed water and the resin are characterised using infrared spectroscopy, and water uptake is correlated to network polymer features such as polarity and free volume. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：293 / 299
页数：7
相关论文
共 75 条
[1]   Curing characteristics and internal stresses in epoxy coatings: Effect of crosslinking agent [J].
Abdelkader, AF ;
White, JR .
JOURNAL OF MATERIALS SCIENCE, 2005, 40 (08) :1843-1854
[2]   IRREVERSIBLE EFFECTS OF MOISTURE ON THE EPOXY MATRIX IN GLASS-REINFORCED COMPOSITES [J].
ANTOON, MK ;
KOENIG, JL .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1981, 19 (02) :197-212
[3]   SORPTION MODES OF WATER IN GLASSY EPOXIES [J].
APICELLA, A ;
TESSIERI, R ;
DECATALDIS, C .
JOURNAL OF MEMBRANE SCIENCE, 1984, 18 (MAR) :211-225
[4]   EFFECT OF TIME-TEMPERATURE PATH OF CURE ON THE WATER-ABSORPTION OF HIGH TG EPOXY-RESINS [J].
ARONHIME, MT ;
PENG, X ;
GILLHAM, JK ;
SMALL, RD .
JOURNAL OF APPLIED POLYMER SCIENCE, 1986, 32 (02) :3589-3626
[5]   Identification of potential migrants in epoxy phenolic can coatings [J].
Bradley, E. L. ;
Driffield, M. ;
Harmer, N. ;
Oldring, P. K. T. ;
Castle, L. .
INTERNATIONAL JOURNAL OF POLYMER ANALYSIS AND CHARACTERIZATION, 2008, 13 (03) :200-223
[6]   DYNAMIC-MECHANICAL ANALYSIS OF EPOXY COMPOSITES PLASTICIZED BY WATER - ARTIFACT AND REALITY [J].
CHATEAUMINOIS, A ;
CHABERT, B ;
SOULIER, JP ;
VINCENT, L .
POLYMER COMPOSITES, 1995, 16 (04) :288-296
[7]   Three-Dimensional Structure Analysis and Percolation Properties of a Barrier Marine Coating [J].
Chen, Bo ;
Guizar-Sicairos, Manuel ;
Xiong, Gang ;
Shemilt, Laura ;
Diaz, Ana ;
Nutter, John ;
Burdet, Nicolas ;
Huo, Suguo ;
Mancuso, Joel ;
Monteith, Alexander ;
Vergeer, Frank ;
Burgess, Andrew ;
Robinson, Ian .
SCIENTIFIC REPORTS, 2013, 3
[8]   A novel spectroscopic approach to investigate transport processes in polymers: the case of water-epoxy system [J].
Cotugno, S ;
Larobina, D ;
Mensitieri, G ;
Musto, P ;
Ragosta, G .
POLYMER, 2001, 42 (15) :6431-6438
[9]   Molecular interactions in and transport properties of densely cross-linked networks:: A time-resolved FT-IR spectroscopy investigation of the epoxy/H2O system [J].
Cotugno, S ;
Mensitieri, G ;
Musto, P ;
Sanguigno, L .
MACROMOLECULES, 2005, 38 (03) :801-811
[10]  
Ding YF, 2001, MACROMOL CHEM PHYSIC, V202, P2681, DOI 10.1002/1521-3935(20010901)202:13<2681::AID-MACP2681>3.0.CO
12345678