Determination of the spectral sensitivity and temperature dependence of polypropylene crack formation caused by UV-irradiation

被引:17
作者
Geburtig, Anja [1 ]
Wachtendorf, Volker [1 ]
机构
[1] BAM Fed Inst Mat Res & Testing, Berlin, Germany
关键词
Weathering; UV; Temperature; Numerical simulation; ENGINEERING THERMOPLASTICS; PHOTOOXIDATION; ACCELERATION; STABILIZERS;
D O I
10.1016/j.polymdegradstab.2010.06.014
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
For polypropylene of varied stabilization, spectral sensitivity as well as temperature dependence of irradiation caused crack formation was determined in artificial irradiation tests. UV radiant exposure H(UV) necessary to generate crack formation was measured both in spectrally dispersed irradiation and artificial irradiation in a Fluorescent UV lamp device. Dependencies were fitted to a plateau function and an Arrhenius function, respectively, to describe the action of irradiation by response functions. Applied to weather data from Phoenix, the results were compared with respective outdoor exposure results. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2118 / 2123
页数:6
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