Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands

被引：25

作者：

Sanchez, Praxedes ^{[1
,2
,3
]}

Hernandez-Juarez, Martin ^{[4
]}

Rendon, Nuria ^{[1
,2
,3
]}

Lopez-Serrano, Joaquin ^{[1
,2
,3
]}

Santos, Laura L. ^{[1
,2
,3
]}

Alvarez, Eleuterio ^{[1
,2
,3
]}

Paneque, Margarita ^{[1
,2
,3
]}

Suarez, Andres ^{[1
,2
,3
]}

机构：

[1] Inst Invest Quim IIQ, Dept Quim Inorgan, Avda Americo Vespucio 49, Seville 41092, Spain

[2] Ctr Innovac Quim Avanzada ORFEO CINQA CSIC, Avda Americo Vespucio 49, Seville 41092, Spain

[3] Univ Seville, Avda Americo Vespucio 49, Seville 41092, Spain

[4] Univ Autonoma Estado Hidalgo, Ctr Invest Quim, Km 14-5 Carretera Pachuca Tulancingo, Mineral De La Reforrna 42184, Hidalgo, Mexico

来源：

DALTON TRANSACTIONS | 2020年 / 49卷 / 28期

关键词：

ACCEPTORLESS DEHYDROGENATION; REVERSIBLE DEHYDROGENATION; NITROGEN-HETEROCYCLES; HYDROGENATION; BEARING; SYSTEM; MILD;

D O I：

10.1039/d0dt02326d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ru complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts in the hydrogenation and dehydrogenation of N-heterocycles. Reaction of a Ru-CNN(H) complex with an excess of base produces the formation of a Ru(0) derivative, which is observed under catalytic conditions.

引用

页码：9583 / 9587

页数：5

共 32 条

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Zhao, Baoguo ;

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Ding, Kuiling .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (18) :4744-4788

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