Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands

被引：25
作者：
Sanchez, Praxedes [1 ,2 ,3 ]
Hernandez-Juarez, Martin [4 ]
Rendon, Nuria [1 ,2 ,3 ]
Lopez-Serrano, Joaquin [1 ,2 ,3 ]
Santos, Laura L. [1 ,2 ,3 ]
Alvarez, Eleuterio [1 ,2 ,3 ]
Paneque, Margarita [1 ,2 ,3 ]
Suarez, Andres [1 ,2 ,3 ]
机构：
[1] Inst Invest Quim IIQ, Dept Quim Inorgan, Avda Americo Vespucio 49, Seville 41092, Spain
[2] Ctr Innovac Quim Avanzada ORFEO CINQA CSIC, Avda Americo Vespucio 49, Seville 41092, Spain
[3] Univ Seville, Avda Americo Vespucio 49, Seville 41092, Spain
[4] Univ Autonoma Estado Hidalgo, Ctr Invest Quim, Km 14-5 Carretera Pachuca Tulancingo, Mineral De La Reforrna 42184, Hidalgo, Mexico
来源：
DALTON TRANSACTIONS | 2020年 / 49卷 / 28期
关键词：
ACCEPTORLESS DEHYDROGENATION; REVERSIBLE DEHYDROGENATION; NITROGEN-HETEROCYCLES; HYDROGENATION; BEARING; SYSTEM; MILD;
D O I：
10.1039/d0dt02326d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ru complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts in the hydrogenation and dehydrogenation of N-heterocycles. Reaction of a Ru-CNN(H) complex with an excess of base produces the formation of a Ru(0) derivative, which is observed under catalytic conditions.
引用
收藏
页码：9583 / 9587
页数：5
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