Two-step synthesis of di- and tristannylarenes from anilines via an SRN1 mechanism

被引：10

作者：

Silbestri, Gustavo F. ^{[1
]}

Lockhart, Maria T. ^{[1
]}

Chopa, Alicia B. ^{[1
]}

机构：

[1] Univ Nacl Sur, Inst Quim Sur, CONICET, UNS,Dept Quim, Ave Alem 1253,B8000CPB, RA-8000 Bahia Blanca, Buenos Aires, Argentina

来源：

ARKIVOC | 2011年

关键词：

Aryltin; S(RN)1; arylammonium salts; ARYLSTANNANES; ALKYLATION; MERCURY; AMINES; IONS; TIN;

D O I：

10.3998/ark.5550190.0012.718

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis in good yields (71-85%) of di- and tristannylated benzenes from commercially available anilines, involving their conversion to the corresponding aryltrimethylammonium salts followed by the reaction with Me3SnNa 1 in liquid ammonia, is described. The results obtained clearly indicate that the stannylation reactions proceed through an S(RN)1 mechanism.

引用

收藏

页码：210 / 220

页数：11

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