Efficient synthesis of 2-iodo and 2-dicyanomethyl derivatives of thiophene, selenophene, tellurophene, and thieno[3,2-b]thiophene

被引:26
作者
Takahashi, K
Tarutani, S
机构
[1] Department of Chemistry, Graduate School of Science, Tohoku University
关键词
D O I
10.3987/COM-96-7517
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An effective synthesis of 2-iodothiophene, 2-iodotellurophene, and 2-iodothieno[3,2-b]thiophene and a Pd-catalyzed carbon-carbon coupling reaction of these iodo derivatives as well as 2-iodoselenophene with malononitrile affording novel thienyl-, tellurienyl-, thieno[3,2-b]thienyl-, and selenienylmalononitrile are described. These heteroarylmalononitriles are important synthons for the preparation of 2-dicyanomethylene-2,5-dihydroheterophene chromophores.
引用
收藏
页码:1927 / 1935
页数:9
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