Supercritical carbon dioxide and poly(ethylene glycol): an environmentally benign biphasic solvent system for aerobic oxidation of styrene

被引：74
作者：
Wang, Jin-Quan [1 ]
Cai, Fei [1 ]
Wang, Er [1 ]
He, Liang-Nian [1 ]
机构：
[1] Nankai Univ, Inst Elemento Organ Chem, State Key Lab Elemento Organ Chem, Tianjin 300071, Peoples R China
来源：
GREEN CHEMISTRY | 2007年 / 9卷 / 08期
关键词：
D O I：
10.1039/b701875d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Aerobic oxidation of styrene catalyzed by PdCl2/CuCl can be smoothly performed in the supercritical carbon dioxide and poly( ethylene glycol) biphasic system. A high conversion of styrene and yield of acetophenone were obtained in the presence of a relatively low catalyst loading. This environmentally benign biphasic catalytic system can be applied to the Wacker oxidation of various alkenes. Furthermore, the PdCl2-mediated oxidation of styrene was preferentially converted into benzaldehyde using a biphasic scCO(2)/PEG system. The PEG could effectively immobilize and stabilize the catalysts. The present biphasic system could facilitate product separation and catalyst recycling. The effects of the reaction parameters such as solvent and CO2 pressure were also investigated in detail.
引用
收藏
页码：882 / 887
页数：6
相关论文
共 50 条
[31]   The influence of carbon dioxide cosolvent on solubility in poly(ethylene glycol) [J].
Michael T. Huber ;
John M. Stubbs .
Theoretical Chemistry Accounts, 2012, 131
[32]   Poly(ethylene glycol): an Alternative Solvent for the Synthesis of Cyclic Carbonate from Vicinal Halohydrin and Carbon Dioxide [J].
Wang, Jing-Lun ;
He, Liang-Nian ;
Dou, Xiao-Yong ;
Wu, Fang .
AUSTRALIAN JOURNAL OF CHEMISTRY, 2009, 62 (08) :917-920
[33]   The influence of carbon dioxide cosolvent on solubility in poly(ethylene glycol) [J].
Huber, Michael T. ;
Stubbs, John M. .
THEORETICAL CHEMISTRY ACCOUNTS, 2012, 131 (10) :1-6
[34]   Dyeing of poly(ethylene terephthalate) fibers in supercritical carbon dioxide [J].
Bach, E ;
Cleve, E ;
Schollmeyer, E .
HIGH PRESSURE CHEMICAL ENGINEERING, 1996, 12 :581-586
[35]   Environmentally benign electroless nickel plating using supercritical carbon-dioxide on hydrophilically modified acrylonitrile-butadiene-styrene [J].
Tengsuwan, Siwach ;
Ohshima, Masahiro .
APPLIED SURFACE SCIENCE, 2014, 311 :189-200
[36]   The sorption properties of supercritical carbon dioxide in poly (ethylene glycol) and poly (ethylene oxide) with high-pressure thermogravimetry-differential thermal analysis [J].
Hata, K .
KOBUNSHI RONBUNSHU, 2001, 58 (12) :714-717
[37]   FluoRuGel: a versatile catalyst for aerobic alcohol oxidation in supercritical carbon dioxide [J].
Ciriminna, Rosaria ;
Campestrini, Sandro ;
Pagliaro, Mario .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2006, 4 (13) :2637-2641
[38]   Solubility of Ethylene Glycol in Supercritical Carbon Dioxide at Pressures up to 19.0 MPa [J].
Jiang, Chun-yue ;
Sun, Zhi-juan ;
Pan, Qin-min ;
Pi, Jian-biao .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2012, 57 (06) :1794-1802
[39]   Drying induced phase separation in poly(styrene)-poly(ethylene glycol)-chlorobenzene system [J].
Sharma, Jyoti ;
Arya, Raj Kumar ;
Ahuja, Sanjeev .
JOURNAL OF POROUS MATERIALS, 2019, 26 (04) :1043-1057
[40]   Drying induced phase separation in poly(styrene)–poly(ethylene glycol)–chlorobenzene system [J].
Jyoti Sharma ;
Raj Kumar Arya ;
Sanjeev Ahuja .
Journal of Porous Materials, 2019, 26 :1043-1057
12345