Carbon-Tungsten Disulfide Composite Bilayer Separator for High Performance Lithium-Sulfur Batteries

被引：52

作者：

Ali, Shamshad ^{[1
,2
]}

Waqas, Muhammad ^{[1
,3
]}

Jing, Xiaopeng ^{[1
]}

Chen, Ning ^{[1
]}

Chen, Dongjiang ^{[1
]}

Xiong, Jie ^{[2
]}

He, Weidong ^{[1
,2
,4
]}

机构：

[1] Univ Elect Sci & Technol, Sch Phys, Chengdu 611731, Sichuan, Peoples R China

[2] Univ Elect Sci & Technol, State Key Lab Elect Thin Films & Integrated Devic, Chengdu 611731, Sichuan, Peoples R China

[3] Sukkur IBA Univ, Dept Elect Engn, Sukkur 65200, Pakistan

[4] Harbin Inst Technol, Ctr Composite Mat & Struct, Harbin 150001, Heilongjiang, Peoples R China

来源：

ACS APPLIED MATERIALS & INTERFACES | 2018年 / 10卷 / 46期

关键词：

lithium-sulfur battery; bilayer separator; high-capacity; cost-effectiveness; carbon-tungsten disulfide composite; polysulfide adsorption; CYCLE-LIFE; NANOFIBERS; CATHODES;

D O I：

10.1021/acsami.8b12682

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

A bilayer separator based on cost-effective carbon tungsten disulfide composite and commercial separators is developed in this work. The C-WS2 separator reduces the shuttling effect and increases the cycle life of the battery because of the excellent adsorption capability of polar WS2 to polysulfides. Furthermore, conductive carbon substantially enhances the ionic conductivity of (1 X 10(-3) S cm(-1)). The cell with the C-WS2 separator delivers an excellent discharge capacity of 996 mA h g(-1) at 1 C and retained at 416 mA h g(-1) after runs over 1000 cycles with a 0.045% capacity decay per cycle. The work provides insights into high-capacity lithium-sulfur batteries with cost-effectiveness.

引用

页码：39417 / 39421

页数：5

共 30 条

[1] Highly Efficient PVDF-HFP/Colloidal Alumina Composite Separator for High-Temperature Lithium-Ion Batteries [J].

Ali, Shamshad ;

Tan, Chao ;

Waqas, Muhammad ;

Lv, Weiqiang ;

Wei, Zhaohuan ;

Wu, Songhao ;

Boateng, Bismark ;

Liu, Jingna ;

Ahmed, Junaid ;

Xiong, Jie ;

Goodenough, John B. ;

He, Weidong .

ADVANCED MATERIALS INTERFACES, 2018, 5 (05)

[2]

Bruce PG, 2012, NAT MATER, V11, P19, DOI [10.1038/NMAT3191, 10.1038/nmat3191]

[3] Aligned carbon nanotube/sulfur composite cathodes with high sulfur content for lithium-sulfur batteries [J].

Cheng, Xin-Bing ;

Huang, Jia-Qi ;

Zhang, Qiang ;

Peng, Hong-Jie ;

Zhao, Meng-Qiang ;

Wei, Fei .

NANO ENERGY, 2014, 4 :65-72

[4] Bifunctional Separator with a Light-Weight Carbon-Coating for Dynamically and Statically Stable Lithium-Sulfur Batteries [J].

Chung, Sheng-Heng ;

Manthiram, Arumugam .

ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (33) :5299-5306

[5] High-Performance Li-S Batteries with an Ultra-lightweight MWCNT-Coated Separator [J].

Chung, Sheng-Heng ;

Manthiram, Arumugam .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2014, 5 (11) :1978-1983

[6] Morphology and atomic-scale structure of single-layer WS2 nanoclusters [J].

Fuchtbauer, Henrik G. ;

Tuxen, Anders K. ;

Moses, Poul G. ;

Topsoe, Henrik ;

Besenbacher, Flemming ;

Lauritsen, Jeppe V. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (38) :15971-15980

[7] Permselective Graphene Oxide Membrane for Highly Stable and Anti-Self-Discharge Lithium-Sulfur Batteries [J].

Huang, Jia-Qi ;

Zhuang, Ting-Zhou ;

Zhang, Qiang ;

Peng, Hong-Jie ;

Chen, Cheng-Meng ;

Wei, Fei .

ACS NANO, 2015, 9 (03) :3002-3011

[8] Advances in Li-S batteries [J].

Ji, Xiulei ;

Nazar, Linda F. .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (44) :9821-9826

[9] A carbon nanofiber@mesoporous δ-MnO2 nanosheet-coated separator for high-performance lithium-sulfur batteries [J].

Lai, Yanqing ;

Wang, Peng ;

Qin, Furong ;

Xu, Ming ;

Li, Jie ;

Zhang, Kai ;

Zhang, Zhian .

ENERGY STORAGE MATERIALS, 2017, 9 :179-187

[10] Multi- Functional Layered WS2 Nanosheets for Enhancing the Performance of Lithium-Sulfur Batteries [J].

Lei, Tianyu ;

Chen, Wei ;

Huang, Jianwen ;

Yan, Chaoyi ;

Sun, Haoxuan ;

Wang, Chao ;

Zhang, Wanli ;

Li, Yanrong ;

Xiong, Jie .

ADVANCED ENERGY MATERIALS, 2017, 7 (04)

← 1 2 3 →