(18-Crown-6)(trifluoromethanesulfonato)sodium

被引：2

作者：

Phan, Hien Ngoc ^{[1
]}

Lerner, Hans-Wolfram ^{[1
]}

Bolte, Michael ^{[1
]}

机构：

[1] JW Goethe Univ Frankfurt, Inst Anorgan Chem, D-60438 Frankfurt, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

CRYSTAL-STRUCTURE; CONDUCTIVITY;

D O I：

10.1107/S1600536810025961

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Na(CF3O3S)(C12H24O6)], features a sodium cation that is coordinated by eight O atoms in an irregular hexagonal bipyramidal environment. The equatorial positions are occupied by the six O atoms of an 18-crown-6 ether ring. In the axial positions, there is one O atom of a trifluoromethanesulfonate anion and an ether O atom of a symmetry-equivalent crown ether ring. In this way, centrosymmetric dimers are formed.

引用

页码：M893 / U338

页数：13

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