Synthesis and characterization of phenol-formaldehyde resin using enzymatic hydrolysis lignin

被引：99
作者：
Qiao, Wei [1 ]
Li, Shujun [1 ]
Guo, Guowan [1 ]
Han, Shiyan [1 ]
Ren, Shixue [1 ]
Ma, Yanli [1 ]
机构：
[1] Northeast Forestry Univ, Key Lab Biobased Mat Sci & Technol, Minist Educ, Harbin 150040, Peoples R China
来源：
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2015年 / 21卷
关键词：
Enzymatic hydrolysis lignin; Phenol-formaldehyde resin; Adhesive strength; Microstructure; Purification; AMMONIUM LIGNOSULFONATE; RESOL RESINS;
D O I：
10.1016/j.jiec.2014.06.016
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Enzymatic hydrolysis lignin (EHL) was utilized to partially replace phenol for preparing phenolformaldehyde (PF) resin. The influence of lignin substitution rate on the properties of the lignin-modified phenol-formaldehyde (LPF) resin was investigated. Lignin substitution of 60 wt% did not deteriorate the adhesive strength of PF resin. FTIR analysis of the resins revealed that the incorporation of EHL made no big difference in chemical structure, but led to a deteriorated thermal resistance. The comparison between LPF and bio-ethanol production residue-modified phenol-formaldehyde (RPF) resins elucidated that the purification process was beneficial for its higher substitution application and better performance of adhesive. (C) 2014 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
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收藏
页码：1417 / 1422
页数：6
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