CuInSe2 formation through Cu2Se-In3Se2 multilayer structures prepared by thermal evaporation technique

被引:7
作者
Mohan, A. [1 ]
Rajesh, S. [2 ]
Srikesh, G. [3 ]
机构
[1] Karunya Univ, Dept Phys, Thin Film Lab, Coimbatore 641114, Tamil Nadu, India
[2] Karunya Univ, Dept Nanosci & Technol, Coimbatore 641114, Tamil Nadu, India
[3] Karunya Univ, Dept Chem, Coimbatore 641114, Tamil Nadu, India
关键词
Thermal evaporation; Quantum size effect; Annealing; Photoluminescence; FILM SOLAR-CELLS; THIN-FILMS; RAMAN-SPECTROSCOPY; OPTICAL-PROPERTIES;
D O I
10.1016/j.spmi.2016.01.034
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The current study investigates the Cu2Se/In3Se2 multilayer structure deposited by thermal evaporation technique for CIS solar cells with different number of layers. The X-ray diffraction pattern reveals that the layer thickness improves the crystallinity and the formation of CIS for the 30 layer films through photoluminescence (PL) emission. The optical band gap values are found to be 2.87 eV and 2.79 eV for 5 and 10 period films respectively. The splitted band gap ranging 1.30 and 2.25 eV for 15 periods and decrease in the band gap values are due to large grains. This splitting is due to quantum size effect and CIS composite formation. The vibration frequency at 174.54 cm(-1) is evident for formation of CuInSe2 Chalcopyrite phase. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:261 / 268
页数:8
相关论文
共 28 条
[21]   Structural and optical properties of ZnSe thin films stacked with PbSe submonolayers [J].
Parvathi, M. Manonmani ;
Arivazhagan, V. ;
Rajesh, S. .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2014, 116 (04) :1773-1778
[22]   Solution-based synthesis of high yield CZTS (Cu2ZnSnS4) spherical quantum dots [J].
Rajesh, G. ;
Muthukumarasamy, N. ;
Subramanian, E. P. ;
Venkatraman, M. R. ;
Agilan, S. ;
Ragavendran, V. ;
Thambidurai, M. ;
Velumani, S. ;
Yi, Junsin ;
Velauthapillai, Dhayalan .
SUPERLATTICES AND MICROSTRUCTURES, 2015, 77 :305-312
[23]   Multilayer Si/Ge thin films with quantum confinement effects for photovoltaic applications [J].
Shah, Salman Ali ;
Khan, Abdul Faheem ;
Khan, AsadUllah ;
Rahim, N. A. ;
Mehmood, Mazhar .
APPLIED SURFACE SCIENCE, 2014, 296 :185-188
[24]  
Tauc J., 1979, Amorphous and Liquid Semiconductors
[25]   Effect of composition modulation on the structural and optical properties of Si/Ge bilayers [J].
Tripathi, S. ;
Sharma, A. ;
Chaudhari, S. M. ;
Shripathi, T. .
SOLID STATE COMMUNICATIONS, 2009, 149 (1-2) :25-30
[26]   Characterization of vacuum-evaporated ZnSe thin films [J].
Venkatachalam, S. ;
Jeyachandran, Y. L. ;
Sureshkumar, P. ;
Dhayalraj, A. ;
Mangalaraj, D. ;
Narayandass, Sa. K. ;
Velumani, S. .
MATERIALS CHARACTERIZATION, 2007, 58 (8-9) :794-799
[27]   STRAIN-INDUCED CRYSTALLIZATION .3. THEORY [J].
YEH, GSY ;
HONG, KZ .
POLYMER ENGINEERING AND SCIENCE, 1979, 19 (06) :395-400
[28]   Raman spectroscopy of CuInSe2 thin films prepared by selenization [J].
Zaretskaya, EP ;
Gremenok, VF ;
Riede, V ;
Schmitz, W ;
Bente, K ;
Zalesski, VB ;
Ermakov, O .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2003, 64 (9-10) :1989-1993