A fluorescent sensor array for saccharides based on boronic acid appended bipyridinium salts

被引:134
作者
Schiller, Alexander [1 ]
Wessling, Ritchie A. [1 ]
Singaram, Bakthan [1 ]
机构
[1] Univ Calif Santa Cruz, Dept Chem & Biochem, Santa Cruz, CA 95064 USA
关键词
boronic acids; carbohydrates; fluorescence; sensors; viologens;
D O I
10.1002/anie.200701888
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Graph Presented) That's discrimination! An array of boronic acid appended bipyridinium salts (BBVs) as receptor units is able to distinguish twelve saccharides in aqueous solution and at neutral pH values by a fluorescent-indicator displacement assay. The picture shows the fluorescence increase of a fluorescent dye with BBV receptors after adding saccharides (D-ribose (Rib), D-glucose (Glc), D-fructose (Fru), melibiose (Mel), and lactulose (Lal)). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:6457 / 6459
页数:3
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