Highly effective synthesis of vinylfunctionalised cubic silsesquioxanes

被引：29

作者：

Zak, Patrycja ^{[1
]}

Marciniec, Bogdan ^{[1
]}

Majchrzak, Mariusz ^{[1
]}

Pietraszuk, Cezary ^{[1
]}

机构：

[1] Adam Mickiewicz Univ, Fac Chem, PL-60780 Poznan, Poland

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2011年 / 696卷 / 04期

关键词：

Homogeneous catalysis; Metathesis; Coupling; Silicon; Ruthenium; OCTAVINYLSILSESQUIOXANE; FUNCTIONALIZATION; SILYLATION; METATHESIS;

D O I：

10.1016/j.jorganchem.2010.10.021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of functionalised cubic monovinylheptaisobutylsilsesquioxanes and octavinylsilsesquioxanes were obtained via efficient and highly stereoselective cross-metathesis and silylative coupling with substituted styrenes. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：887 / 891

页数：5

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