Highly effective synthesis of vinylfunctionalised cubic silsesquioxanes

被引：29

作者：

Zak, Patrycja ^{[1
]}

Marciniec, Bogdan ^{[1
]}

Majchrzak, Mariusz ^{[1
]}

Pietraszuk, Cezary ^{[1
]}

机构：

[1] Adam Mickiewicz Univ, Fac Chem, PL-60780 Poznan, Poland

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2011年 / 696卷 / 04期

关键词：

Homogeneous catalysis; Metathesis; Coupling; Silicon; Ruthenium; OCTAVINYLSILSESQUIOXANE; FUNCTIONALIZATION; SILYLATION; METATHESIS;

D O I：

10.1016/j.jorganchem.2010.10.021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of functionalised cubic monovinylheptaisobutylsilsesquioxanes and octavinylsilsesquioxanes were obtained via efficient and highly stereoselective cross-metathesis and silylative coupling with substituted styrenes. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：887 / 891

页数：5

共 26 条

[1]

[Anonymous], MAT RES SOC S P

[2] Cubic silsesquioxanes for use in solution processable organic light emitting diodes (OLED) [J].

Chan, Khai Leok ;

Sonar, Prashant ;

Sellinger, Alan .

JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (48) :9103-9120

[3] Synthesis of functional cubes from octavinylsilsesquioxane (OVS) [J].

Cheng, Ge ;

Vautravers, Nicolas R. ;

Morris, Russell E. ;

Cole-Hamilton, David J. .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2008, 6 (24) :4662-4667

[4] Recent Developments in the Chemistry of Cubic Polyhedral Oligosilsesquioxanes [J].

Cordes, David B. ;

Lickiss, Paul D. ;

Rataboul, Franck .

CHEMICAL REVIEWS, 2010, 110 (04) :2081-2173

[5]

FEHER FJ, 1997, CHEM COMMUN, V1185

[6]

Grubbs R.H., 2003, HDB METATHESIS, V3

[7] Functionalization of octavinylsilsesquioxane by ruthenium-catalyzed silylative coupling versus cross-metathesis [J].

Itami, Y ;

Marciniec, B ;

Kubicki, M .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (05) :1239-1248

[8]

Lebeau B, 2002, MATER RES SOC SYMP P, V726, P129

[9] Organic-inorganic hybrids based on pyrene functionalized octavinylsilsesquioxane cores for application in OLEDs [J].

Lo, Mee Yoon ;

Zhen, Changgua ;

Lauters, Michael ;

Jabbour, Ghassan E. ;

Sellinger, Alan .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (18) :5808-+

[10] Silsesquioxane-based nanocomposite dendrimers with photo-luminescent and charge transport properties [J].

Lo, Mee Yoon ;

Ueno, Kazunori ;

Tanabe, Hiroshi ;

Sellinger, Alan .

CHEMICAL RECORD, 2006, 6 (03) :157-168

← 1 2 3 →