Photodegradation Activity of Poly(ethylene oxide-b-ε-caprolactone)-Templated Mesoporous TiO2 Coated with Au and Pt

被引:4
作者
Chu, Wei-Cheng [1 ]
Kim, Jeonghun [2 ,3 ,4 ]
Kim, Minjun [3 ,4 ]
Alshehri, Abdulmohsen Ali [5 ]
Alghamidi, Yousef Gamaan [5 ]
Alzahrani, Khalid Ahmed [5 ]
Yamauchi, Yusuke [2 ,3 ,4 ,6 ]
Malgras, Victor [7 ,8 ]
Ku, Shiao-Wei [1 ,9 ]
机构
[1] Natl Sun Yat Sen Univ, Ctr Crystal Res, Dept Mat & Optoelect Sci, Kaohsiung 80424, Taiwan
[2] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Key Lab Ecochem Engn, Qingdao 266042, Peoples R China
[3] Univ Queensland, Sch Chem Engn, Brisbane, Qld 4072, Australia
[4] Univ Queensland, AIBN, Brisbane, Qld 4072, Australia
[5] King Abdulaziz Univ, Dept Chem, Jeddah 21589, Saudi Arabia
[6] Kyung Hee Univ, Dept Plant & Environm New Resources, 1732 Deogyeong Daero, Yongin 446701, Gyeonggi Do, South Korea
[7] NIMS, ICYS, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan
[8] NIMS, Int Ctr Mat Nanoarchitecton MANA, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan
[9] Kaohsiung Med Univ, Dept Med & Appl Chem, Kaohsiung 807, Taiwan
关键词
Mesoporous; Nanocomposite; Soft-Template; TiO2; Photodegradation; Rhodamine; 6G; NANOPARTICLES; SILICA; PD;
D O I
10.1166/jnn.2020.18572
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Mesoporous TiO2 films are synthesized through evaporation-induced self-assembly using poly(ethylene oxide-b-epsilon-caprolactone) diblock copolymers as a soft-template. Using small-angle X-ray scattering and scanning electron microscopy, we investigate the effect of the TiO2/PEO-b-PCL ratio on the resulting nanoarchitectonic structure. After sputter-coating Au and Pt layers, these Au/TiO2 and Pt/TiO2 nanocomposite films display drastically enhanced photodegradation of rhodamine 6G under ultraviolet irradiation, due to the metal films inhibiting the rapid recombination of photogenerated charge carriers.
引用
收藏
页码:5276 / 5281
页数:6
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