A true nanocomposite Single crystalline Au nanoparticles on single crystalline Fe3O4 nanoparticles

被引:8
作者
Cui, Zhi-Min [2 ]
Chen, Zhe [1 ]
Jiang, Ling-Yan [1 ]
Song, Wei-Guo [1 ]
Jiang, Lei [1 ,2 ]
机构
[1] Chinese Acad Sci, Inst Chem, Natl Lab Mol Sci, Beijing 100190, Peoples R China
[2] Beihang Univ, Sch Chem & Environm, Beijing 100191, Peoples R China
基金
中国国家自然科学基金;
关键词
Nanocomposites; Nanocrystalline materials; Crystal structure; CO oxidation; Fe3O4; nanoparticles; LOW-TEMPERATURE OXIDATION; CARBON-MONOXIDE; GOLD CATALYSTS; CO;
D O I
10.1016/j.matlet.2010.09.032
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
An Au/Fe3O4 nanocomposite catalyst was fabricated through a simple deposition-precipitation method The Au/Fe3O4 nanocomposite is a true nanocomposite that has single crystalline Au nanoparticles supported on single crystalline Fe3O4 nanoparticles Lattice fringes from both Au and Fe3O4 single nanoparticles were simultaneously observed by transmission electron microscope (TEM) This nanocomposite catalyst showed much high activity in low temperature CO oxidation reaction The Au/Fe3O4 nanocomposite catalyst reaches 100% CO conversion at 40 C In comparison Au/commercial Fe3O4 catalyst needs 375 C to convert CO This Au/Fe3O4 nanocomposite is an ideal sample to study synergetic effect between the catalyst and the support at nanoscale (C) 2010 Elsevier B V All rights reserved
引用
收藏
页码:82 / 84
页数:3
相关论文
共 15 条
[1]   Catalysis by gold [J].
Bond, GC ;
Thompson, DT .
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1999, 41 (3-4) :319-388
[2]   Nanocrystalline CeO2 increases the activity of an for CO oxidation by two orders of magnitude [J].
Carrettin, S ;
Concepción, P ;
Corma, A ;
Nieto, JML ;
Puntes, VF .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (19) :2538-2540
[3]   High-Yield Gas-Liquid Interfacial Synthesis of Highly Dispersed Fe3O4 Nanocrystals and Their Application in Lithium-Ion Batteries [J].
Cui, Zhi-Min ;
Hang, Ling-Yan ;
Song, Wei-Guo ;
Guo, Yu-Guo .
CHEMISTRY OF MATERIALS, 2009, 21 (06) :1162-1166
[4]   LOW-TEMPERATURE OXIDATION OF CO OVER GOLD SUPPORTED ON TIO2, ALPHA-FE2O3, AND CO3O4 [J].
HARUTA, M ;
TSUBOTA, S ;
KOBAYASHI, T ;
KAGEYAMA, H ;
GENET, MJ ;
DELMON, B .
JOURNAL OF CATALYSIS, 1993, 144 (01) :175-192
[5]   NOVEL GOLD CATALYSTS FOR THE OXIDATION OF CARBON-MONOXIDE AT A TEMPERATURE FAR BELOW 0-DEGREES-C [J].
HARUTA, M ;
KOBAYASHI, T ;
SANO, H ;
YAMADA, N .
CHEMISTRY LETTERS, 1987, (02) :405-408
[6]   Catalysis - Gold rush [J].
Haruta, M .
NATURE, 2005, 437 (7062) :1098-1099
[7]   GOLD CATALYSTS PREPARED BY COPRECIPITATION FOR LOW-TEMPERATURE OXIDATION OF HYDROGEN AND OF CARBON-MONOXIDE [J].
HARUTA, M ;
YAMADA, N ;
KOBAYASHI, T ;
IIJIMA, S .
JOURNAL OF CATALYSIS, 1989, 115 (02) :301-309
[8]   Gold catalysis [J].
Hashmi, A. Stephen K. ;
Hutchings, Graham J. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (47) :7896-7936
[9]   Synthetic Tuning of the Catalytic Properties of Au-Fe3O4 Nanoparticles [J].
Lee, Youngmin ;
Angel Garcia, Miguel ;
Huls, Natalie A. Frey ;
Sun, Shouheng .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (07) :1271-1274
[10]   Synthesis and one-dimensional self-assembly of acicular nickel nanocrystallites under magnetic fields [J].
Niu, HL ;
Chen, QW ;
Ning, M ;
Jia, YS ;
Wang, XJ .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (13) :3996-3999