GILDES model studies of aqueous chemistry .2. The corrosion of zinc in gaseous exposure chambers

被引：37

作者：

Farrow, LA

Graedel, TE

Leygraf, C

机构：

[1] AT&T BELL LABS, LUCENT TECHNOL, MURRAY HILL, NJ 07974 USA

[2] ROYAL INST TECHNOL, S-10044 STOCKHOLM, SWEDEN

来源：

CORROSION SCIENCE | 1996年 / 38卷 / 12期

关键词：

zinc; modelling studies; atmospheric corrosion;

D O I：

10.1016/S0010-938X(96)00081-9

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The GILDES model has been used to perform the first theoretical mechanistic study of the atmospheric corrosion of zinc in a controlled environment. Detailed comparisons are made of model results with laboratory data for short-term (0-1000 min) and long-term (0-680 h) exposures of zinc to SO2, NO2 and O-3 at high relative humidities. The agreement of theory and experiment is excellent, indicating that the model has captured the principal processes (especially ligand-promoted dissolution) involved in the corrosion of zinc under these conditions. Copyright (C) 1996 Published by Elsevier Science Ltd

引用

页码：2181 / 2199

页数：19

共 65 条

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