An enhanced stable-structure core-shell coaxial carbon nanofiber web as a direct anode material for lithium-based batteries

被引:31
作者
Liu, Bingxue [1 ]
Yu, Yunhua [1 ]
Chang, Jie [1 ]
Yang, Xiujuan [1 ]
Wu, Dezhen [1 ]
Yang, Xiaoping [1 ]
机构
[1] Beijing Univ Chem Technol, Minisrry Educ, Key Lab Carbon Fiber & Funct Polymers, Beijing 100029, Peoples R China
基金
中国国家自然科学基金;
关键词
Enhanced stable-structure; Coaxial; Carbon nanofibers; Anode; LI-ION BATTERIES; ELECTROCHEMICAL ENERGY-STORAGE; FABRICATION; COMPOSITE;
D O I
10.1016/j.elecom.2011.03.009
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A new core-shell coaxial carbon nanofibers web (C-CNFW), exhibiting high carbon purity (without any binders), structural integrity, enhanced stability under different current loads, long cycling life, large reversible capacity (over 520 mA h g(-1)), excellent capacity retention and good rate capability, is fabricated by coaxial electrospinning and subsequent carbonization. It is envisaged that the superior electrochemical properties of C-CNFW will make it a promising candidate for the anode material of high-power lithium-ion batteries (LIBs), owing to the unique combinative effects of core carbon material from mineral oil and sheath carbon material from PAN. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:558 / 561
页数:4
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