Visible light-mediated C-P bond formation reactions

被引：194

作者：

Cai, Bao-Gui ^{[1
]}

Xuan, Jun ^{[1
]}

Xiao, Wen-Jing ^{[2
]}

机构：

[1] Anhui Univ, Anhui Prov Key Lab Chem Inorgan Organ Hybrid Func, Coll Chem & Chem Engn, Hefei 230601, Anhui, Peoples R China

[2] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Coll Chem, Wuhan 430079, Hubei, Peoples R China

来源：

SCIENCE BULLETIN | 2019年 / 64卷 / 05期

基金：

中国国家自然科学基金;

关键词：

C-P bond formation; Organophosphorus compounds; Photoredox catalysis; Visible light; PHOTOREDOX CATALYSIS; UNACTIVATED ALKENES; CASCADE REACTIONS; METAL-FREE; PHOTOCHEMICAL ACTIVITY; FORMING REACTIONS; PHOSPHINE OXIDES; FUNCTIONALIZATION; PHOSPHORYLATION; PHOSPHONYLATION;

D O I：

10.1016/j.scib.2019.02.002

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Organophosphorus compounds have attracted continuous attention in materials science, agrochemical and pharmaceutical fields due to their unique bioactivities. Thus, the development of novel and robust manners for the construction new C-P bond has therefore gained great interests in synthetic organic chemistry. Because of their intrinsic sustainability and green chemistry character, visible light-induced photoredox catalysis has been widely applied in the construction of new chemical bonds, including the formation of C-P bond. In this review, we summarized recent achievements in C-P bond formation reactions initiated by visible light-induced photoredox catalysis, which mainly focusing on the discussion of reaction design and the mechanism. (C) 2019 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.

引用

页码：337 / 350

页数：14

共 83 条

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