Silyl Cation Mediated Conversion of CO2 into Benzoic Acid, Formic Acid, and Methanol

被引：114
|
作者：
Schaefer, Andre [1 ]
Saak, Wolfgang [1 ]
Haase, Detlev [1 ]
Mueller, Thomas [1 ]
机构：
[1] Carl von Ossietzky Univ Oldenburg, Inst Reine & Angew Chem, D-26111 Oldenburg, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 12期
关键词：
CO2; reduction; density functional calculations; Lewis acids; NMR spectroscopy; silyl cations; FRUSTRATED LEWIS PAIRS; N-HETEROCYCLIC CARBENES; CARBON-DIOXIDE; ORGANOSILICON COMPOUNDS; AROMATIC-ALDEHYDES; TRANSFORMATION; ORGANOCATALYSTS; OPPORTUNITIES; CHALLENGES; REDUCTION;
D O I：
10.1002/anie.201107958
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
As you like it: The choice of solvents and substituents at the silicon atom determine what product is formed from carbon dioxide after electrophilic activation by silyl cations (see scheme). Benzoic acid as well as the C-1 building blocks formic acid and methanol are on the product tableau. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：2981 / 2984
页数：4
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