Photoelectron Imaging of Ag-(H2O)x and AgOH-(H2O)y (x=1,2, y=0-4)

被引：11

作者：

Chi, Chaoxian ^{[1
]}

Xie, Hua ^{[2
]}

Li, Yuzhen ^{[1
]}

Cong, Ran ^{[2
]}

Zhou, Mingfei ^{[1
]}

Tang, Zichao ^{[2
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysts & Innovat Mat, Shanghai 200433, Peoples R China

[2] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2011年 / 115卷 / 21期

基金：

中国国家自然科学基金;

关键词：

TRANSITION-METAL HYDROXIDES; EFFECTIVE CORE POTENTIALS; DER-WAALS COMPLEXES; AB-INITIO; MOLECULAR CALCULATIONS; NEGATIVE-IONS; INFRARED-SPECTROSCOPY; ELECTRON-AFFINITIES; WEAK-INTERACTIONS; BASIS-SETS;

D O I：

10.1021/jp202497x

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The photoelectron images of Ag-(H2O)(x) (x = 1,2) and AgOH-(H2O)(y) (y = 0-4) are reported. The Ag-(H2O)(1,2) anionic complexes have similar characteristics to the other two coinage metal-water complexes that can be characterized as metal atomic anion solvated by water molecules with the electron mainly localized on the metal. The vibrationally well-resolved photoelectron spectrum allows the adiabatic detachment energy (ADE) and vertical detachment energy (VDE) of AgOH- to be determined as 1.18(2) and 1.24(2) eV, respectively. The AgOH- anion interacts more strongly with water molecules than the Ag- anion. The photoelectron spectra of Ag-(H2O)(x) and AgOH-(H2O)(y) show a gradual increase in ADE and VDE with increasing x and y due to the solvent stabilization.

引用

页码：5380 / 5386

页数：7

共 67 条

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