Redox-Active Pincer Ligands

被引：10

作者：

van der Vlugt, Jarl Ivar ^{[1
]}

机构：

[1] Carl von Ossietzky Univ Oldenburg, Bioinspired Coordinat Chem & Catalysis Grp, Inst Chem, Oldenburg, Germany

来源：

METAL-LIGAND CO-OPERATIVITY: CATALYSIS AND THE PINCER-METAL PLATFORM | 2021年 / 68卷

关键词：

Homogeneous catalysis; Pincer ligand; Redox-active ligand; Single-electron transfer; Transition metals; TRANSITION-METAL-COMPLEXES; C-H ACTIVATION; ELECTRON-SPIN-RESONANCE; CORE RESTING STATE; DINITROGEN COMPLEXES; PALLADIUM COMPLEXES; NICKEL-COMPLEXES; IRON COMPLEXES; NON-INNOCENCE; HETEROBIMETALLIC COMPLEXES;

D O I：

10.1007/3418_2020_68

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review aims to provide a comprehensive overview of the emerging field of redox-active pincer ligands. As such, following a short general introduction on ligand-centred redox activity, the recent literature is discussed in two separate sections. The first deals with ligand platforms that predominantly display reductive chemistry from the 'parent' scaffold; the second focusses more on systems that readily undergo oxidative chemistry. Fundamental stoichiometric reactivity as well as, where explored, catalytic applications will be discussed. This combined survey hopefully inspires the exploration and uncovering of many new avenues within the realm of redox-active pincer chemistry.

引用

页码：135 / 179

页数：45

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